Functional terpolymers containing vinylphosphonic acid: The synthesis and characterization of poly(vinylphosphonic acid-co-styrene-co-maleic anhydride)

Novel functional temperature‐sensitive amphiphilic P‐containing polymers were synthesized by complex‐radical ternary polymerization of vinylphosphonic acid (VPA), styrene (S), and maleic anhydride (MA). Charge transfer complexes (CTCs), complex‐formation constants (Kc) between acceptor and donor mon...

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Bibliographic Details
Published in:Journal of applied polymer science 2012-09, Vol.125 (5), p.3617-3629
Main Authors: Kavlak, Serap, Güner, Ali, Rzayev, Zakir M. O.
Format: Article
Language:English
Subjects:
Anhydrides
Applied sciences
Charge transfer
complex-formation
Constants
Exact sciences and technology
Materials science
monomer reactivity ratios
Monomers
Organic polymers
Physicochemistry of polymers
Polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
radical polymerization
Reproduction
structure-property relations
Terpolymers
thermal properties
Titration
Viscometry
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Summary:Novel functional temperature‐sensitive amphiphilic P‐containing polymers were synthesized by complex‐radical ternary polymerization of vinylphosphonic acid (VPA), styrene (S), and maleic anhydride (MA). Charge transfer complexes (CTCs), complex‐formation constants (Kc) between acceptor and donor monomer systems and the complexed monomer reactivity ratios were investigated by 1H‐NMR analysis. Contrary to theoretical predictions, the VPA…S complex is more active as compared to MA…S complex in the ternary system since VPA monomer can form the CTC both with S monomer and strong H‐bonded complex with MA monomer. The terpolymer compositions, characterizations, and structure–property relationships of a series of poly(VPA‐co‐S‐co‐MA)s were investigated by GPC, FTIR, Raman, 1H‐NMR, 13C‐NMR, DEPT‐135, 31P‐NMR, TGA‐DSC, DMA, XRD, viscometry, and titration. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
ISSN:0021-8995
1097-4628
DOI:10.1002/app.36522