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A water-soluble acrylamide hydrophobically associating polymer: Synthesis, characterization, and properties as EOR chemical

A water‐soluble acrylamide hydrophobically associating terpolymer for polymer flooding was successfully synthesized via free radical polymerization using acrylamide (AM), acrylic acid (AA), and N,N‐divinylnonadeca‐1,10‐dien‐2‐amine (DNDA) as raw materials. The terpolymer was characterized by IR spec...

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Published in:Journal of applied polymer science 2013-08, Vol.129 (4), p.1888-1896
Main Authors: Lai, Nanjun, Dong, Wan, Ye, Zhongbin, Dong, Jun, Qin, Xiaoping, Chen, Weili, Chen, Ke
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Language:English
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cited_by cdi_FETCH-LOGICAL-c3983-ebc38db78463790ca9365aa091bae46e0ac32b62a90b7a2bb45498cc0fe4f91a3
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creator Lai, Nanjun
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Chen, Ke
description A water‐soluble acrylamide hydrophobically associating terpolymer for polymer flooding was successfully synthesized via free radical polymerization using acrylamide (AM), acrylic acid (AA), and N,N‐divinylnonadeca‐1,10‐dien‐2‐amine (DNDA) as raw materials. The terpolymer was characterized by IR spectroscopy and fluorescence spectra. Compared with partially hydrolyzed polyacryamide (HPAM), the terpolymer showed a stronger link and better dimensional network structure under the environmental scanning electron microscope (ESEM). The results of rheology indicated that the terpolymer (AM‐NaAA‐DNDA) showed an excellent shear‐resistance in high shear rate (1000 s−1) and remarkable temperature‐tolerance (above 110°C). The salt‐resisting experiment revealed that this terpolymer had a better anti‐salt ability. According to the core flooding test, it could be obtained that oil recovery was enhanced more than 15% under conditions of 2000 mg/L terpolymer in the mineralization of 8000 mg/L at 60°C. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
doi_str_mv 10.1002/app.38893
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Appl. Polym. Sci</addtitle><description>A water‐soluble acrylamide hydrophobically associating terpolymer for polymer flooding was successfully synthesized via free radical polymerization using acrylamide (AM), acrylic acid (AA), and N,N‐divinylnonadeca‐1,10‐dien‐2‐amine (DNDA) as raw materials. The terpolymer was characterized by IR spectroscopy and fluorescence spectra. Compared with partially hydrolyzed polyacryamide (HPAM), the terpolymer showed a stronger link and better dimensional network structure under the environmental scanning electron microscope (ESEM). The results of rheology indicated that the terpolymer (AM‐NaAA‐DNDA) showed an excellent shear‐resistance in high shear rate (1000 s−1) and remarkable temperature‐tolerance (above 110°C). The salt‐resisting experiment revealed that this terpolymer had a better anti‐salt ability. 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The salt‐resisting experiment revealed that this terpolymer had a better anti‐salt ability. According to the core flooding test, it could be obtained that oil recovery was enhanced more than 15% under conditions of 2000 mg/L terpolymer in the mineralization of 8000 mg/L at 60°C. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.38893</doi><tpages>9</tpages></addata></record>
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subjects Acrylamide
addition polymerization
Applied sciences
copolymers
Crude oil, natural gas and petroleum products
Crude oil, natural gas, oil shales producing equipements and methods
Energy
Enhanced oil recovery methods
Exact sciences and technology
Fluorescence
Fuels
Materials science
Networks
oil and gas
Oil recovery
Organic polymers
Physicochemistry of polymers
Polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
properties and characterization
Prospecting and production of crude oil, natural gas, oil shales and tar sands
radical polymerization
Raw materials
Reproduction
Scanning electron microscopy
Terpolymers
title A water-soluble acrylamide hydrophobically associating polymer: Synthesis, characterization, and properties as EOR chemical
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