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A water-soluble acrylamide hydrophobically associating polymer: Synthesis, characterization, and properties as EOR chemical
A water‐soluble acrylamide hydrophobically associating terpolymer for polymer flooding was successfully synthesized via free radical polymerization using acrylamide (AM), acrylic acid (AA), and N,N‐divinylnonadeca‐1,10‐dien‐2‐amine (DNDA) as raw materials. The terpolymer was characterized by IR spec...
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Published in: | Journal of applied polymer science 2013-08, Vol.129 (4), p.1888-1896 |
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container_title | Journal of applied polymer science |
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creator | Lai, Nanjun Dong, Wan Ye, Zhongbin Dong, Jun Qin, Xiaoping Chen, Weili Chen, Ke |
description | A water‐soluble acrylamide hydrophobically associating terpolymer for polymer flooding was successfully synthesized via free radical polymerization using acrylamide (AM), acrylic acid (AA), and N,N‐divinylnonadeca‐1,10‐dien‐2‐amine (DNDA) as raw materials. The terpolymer was characterized by IR spectroscopy and fluorescence spectra. Compared with partially hydrolyzed polyacryamide (HPAM), the terpolymer showed a stronger link and better dimensional network structure under the environmental scanning electron microscope (ESEM). The results of rheology indicated that the terpolymer (AM‐NaAA‐DNDA) showed an excellent shear‐resistance in high shear rate (1000 s−1) and remarkable temperature‐tolerance (above 110°C). The salt‐resisting experiment revealed that this terpolymer had a better anti‐salt ability. According to the core flooding test, it could be obtained that oil recovery was enhanced more than 15% under conditions of 2000 mg/L terpolymer in the mineralization of 8000 mg/L at 60°C. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
doi_str_mv | 10.1002/app.38893 |
format | article |
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The terpolymer was characterized by IR spectroscopy and fluorescence spectra. Compared with partially hydrolyzed polyacryamide (HPAM), the terpolymer showed a stronger link and better dimensional network structure under the environmental scanning electron microscope (ESEM). The results of rheology indicated that the terpolymer (AM‐NaAA‐DNDA) showed an excellent shear‐resistance in high shear rate (1000 s−1) and remarkable temperature‐tolerance (above 110°C). The salt‐resisting experiment revealed that this terpolymer had a better anti‐salt ability. According to the core flooding test, it could be obtained that oil recovery was enhanced more than 15% under conditions of 2000 mg/L terpolymer in the mineralization of 8000 mg/L at 60°C. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.38893</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Acrylamide ; addition polymerization ; Applied sciences ; copolymers ; Crude oil, natural gas and petroleum products ; Crude oil, natural gas, oil shales producing equipements and methods ; Energy ; Enhanced oil recovery methods ; Exact sciences and technology ; Fluorescence ; Fuels ; Materials science ; Networks ; oil and gas ; Oil recovery ; Organic polymers ; Physicochemistry of polymers ; Polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; properties and characterization ; Prospecting and production of crude oil, natural gas, oil shales and tar sands ; radical polymerization ; Raw materials ; Reproduction ; Scanning electron microscopy ; Terpolymers</subject><ispartof>Journal of applied polymer science, 2013-08, Vol.129 (4), p.1888-1896</ispartof><rights>Copyright © 2012 Wiley Periodicals, Inc.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3983-ebc38db78463790ca9365aa091bae46e0ac32b62a90b7a2bb45498cc0fe4f91a3</citedby><cites>FETCH-LOGICAL-c3983-ebc38db78463790ca9365aa091bae46e0ac32b62a90b7a2bb45498cc0fe4f91a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27398889$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lai, Nanjun</creatorcontrib><creatorcontrib>Dong, Wan</creatorcontrib><creatorcontrib>Ye, Zhongbin</creatorcontrib><creatorcontrib>Dong, Jun</creatorcontrib><creatorcontrib>Qin, Xiaoping</creatorcontrib><creatorcontrib>Chen, Weili</creatorcontrib><creatorcontrib>Chen, Ke</creatorcontrib><title>A water-soluble acrylamide hydrophobically associating polymer: Synthesis, characterization, and properties as EOR chemical</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>A water‐soluble acrylamide hydrophobically associating terpolymer for polymer flooding was successfully synthesized via free radical polymerization using acrylamide (AM), acrylic acid (AA), and N,N‐divinylnonadeca‐1,10‐dien‐2‐amine (DNDA) as raw materials. The terpolymer was characterized by IR spectroscopy and fluorescence spectra. Compared with partially hydrolyzed polyacryamide (HPAM), the terpolymer showed a stronger link and better dimensional network structure under the environmental scanning electron microscope (ESEM). The results of rheology indicated that the terpolymer (AM‐NaAA‐DNDA) showed an excellent shear‐resistance in high shear rate (1000 s−1) and remarkable temperature‐tolerance (above 110°C). The salt‐resisting experiment revealed that this terpolymer had a better anti‐salt ability. According to the core flooding test, it could be obtained that oil recovery was enhanced more than 15% under conditions of 2000 mg/L terpolymer in the mineralization of 8000 mg/L at 60°C. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</description><subject>Acrylamide</subject><subject>addition polymerization</subject><subject>Applied sciences</subject><subject>copolymers</subject><subject>Crude oil, natural gas and petroleum products</subject><subject>Crude oil, natural gas, oil shales producing equipements and methods</subject><subject>Energy</subject><subject>Enhanced oil recovery methods</subject><subject>Exact sciences and technology</subject><subject>Fluorescence</subject><subject>Fuels</subject><subject>Materials science</subject><subject>Networks</subject><subject>oil and gas</subject><subject>Oil recovery</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>properties and characterization</subject><subject>Prospecting and production of crude oil, natural gas, oil shales and tar sands</subject><subject>radical polymerization</subject><subject>Raw materials</subject><subject>Reproduction</subject><subject>Scanning electron microscopy</subject><subject>Terpolymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp1kU1rFEEQhhtRcN148B80iGAgk_THfLW3JcYYCJv4hcFLU9Nb43bsmR67Z4kT_7y9bpKD4KkO9bwPVbyEvODskDMmjmAYDmVdK_mIzDhTVZaXon5MZmnHs1qp4il5FuM1Y5wXrJyR3wt6AyOGLHq3aRxSMGFy0NkV0vW0Cn5Y-8YacG6iEKM3Fkbbf6eDd1OH4Q39NPXjGqONB9SsIYBJMnubIN8fUOhXdEgODKPFmAT05OJj4rDbKvfIkxZcxOd3c06-vDv5fPw-O784PTtenGdGqlpm2BhZr5qqzktZKWZAybIAYIo3gHmJDIwUTSlAsaYC0TR5kavaGNZi3ioOck5e77zplJ8bjKPubDToHPToN1HzXKqqEIUoE_ryH_Tab0KfrtNcFlKoQlQsUfs7ygQfY8BWD8F2ECbNmd7WoFMN-m8NiX11Z4SYfm4D9MbGh4Co0o9bcE6OdtyNdTj9X6gXl5f35myXsHHEXw8JCD90Wcmq0F-Xp_rqw7crvly-1bX8A0oqp40</recordid><startdate>20130815</startdate><enddate>20130815</enddate><creator>Lai, Nanjun</creator><creator>Dong, Wan</creator><creator>Ye, Zhongbin</creator><creator>Dong, Jun</creator><creator>Qin, Xiaoping</creator><creator>Chen, Weili</creator><creator>Chen, Ke</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130815</creationdate><title>A water-soluble acrylamide hydrophobically associating polymer: Synthesis, characterization, and properties as EOR chemical</title><author>Lai, Nanjun ; Dong, Wan ; Ye, Zhongbin ; Dong, Jun ; Qin, Xiaoping ; Chen, Weili ; Chen, Ke</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3983-ebc38db78463790ca9365aa091bae46e0ac32b62a90b7a2bb45498cc0fe4f91a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Acrylamide</topic><topic>addition polymerization</topic><topic>Applied sciences</topic><topic>copolymers</topic><topic>Crude oil, natural gas and petroleum products</topic><topic>Crude oil, natural gas, oil shales producing equipements and methods</topic><topic>Energy</topic><topic>Enhanced oil recovery methods</topic><topic>Exact sciences and technology</topic><topic>Fluorescence</topic><topic>Fuels</topic><topic>Materials science</topic><topic>Networks</topic><topic>oil and gas</topic><topic>Oil recovery</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>properties and characterization</topic><topic>Prospecting and production of crude oil, natural gas, oil shales and tar sands</topic><topic>radical polymerization</topic><topic>Raw materials</topic><topic>Reproduction</topic><topic>Scanning electron microscopy</topic><topic>Terpolymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lai, Nanjun</creatorcontrib><creatorcontrib>Dong, Wan</creatorcontrib><creatorcontrib>Ye, Zhongbin</creatorcontrib><creatorcontrib>Dong, Jun</creatorcontrib><creatorcontrib>Qin, Xiaoping</creatorcontrib><creatorcontrib>Chen, Weili</creatorcontrib><creatorcontrib>Chen, Ke</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lai, Nanjun</au><au>Dong, Wan</au><au>Ye, Zhongbin</au><au>Dong, Jun</au><au>Qin, Xiaoping</au><au>Chen, Weili</au><au>Chen, Ke</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A water-soluble acrylamide hydrophobically associating polymer: Synthesis, characterization, and properties as EOR chemical</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2013-08-15</date><risdate>2013</risdate><volume>129</volume><issue>4</issue><spage>1888</spage><epage>1896</epage><pages>1888-1896</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>A water‐soluble acrylamide hydrophobically associating terpolymer for polymer flooding was successfully synthesized via free radical polymerization using acrylamide (AM), acrylic acid (AA), and N,N‐divinylnonadeca‐1,10‐dien‐2‐amine (DNDA) as raw materials. The terpolymer was characterized by IR spectroscopy and fluorescence spectra. Compared with partially hydrolyzed polyacryamide (HPAM), the terpolymer showed a stronger link and better dimensional network structure under the environmental scanning electron microscope (ESEM). The results of rheology indicated that the terpolymer (AM‐NaAA‐DNDA) showed an excellent shear‐resistance in high shear rate (1000 s−1) and remarkable temperature‐tolerance (above 110°C). The salt‐resisting experiment revealed that this terpolymer had a better anti‐salt ability. According to the core flooding test, it could be obtained that oil recovery was enhanced more than 15% under conditions of 2000 mg/L terpolymer in the mineralization of 8000 mg/L at 60°C. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.38893</doi><tpages>9</tpages></addata></record> |
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subjects | Acrylamide addition polymerization Applied sciences copolymers Crude oil, natural gas and petroleum products Crude oil, natural gas, oil shales producing equipements and methods Energy Enhanced oil recovery methods Exact sciences and technology Fluorescence Fuels Materials science Networks oil and gas Oil recovery Organic polymers Physicochemistry of polymers Polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts properties and characterization Prospecting and production of crude oil, natural gas, oil shales and tar sands radical polymerization Raw materials Reproduction Scanning electron microscopy Terpolymers |
title | A water-soluble acrylamide hydrophobically associating polymer: Synthesis, characterization, and properties as EOR chemical |
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