From thiophene S -oxides to 7-thiabicyclo[2.2.1]hept-5-enes

Oligocycles with a 7-thiabicyclo[2.2.1]hept-5-ene unit have been prepared stereoselectively by cycloaddition of thiophene S-oxides to alkenes and subsequent deoxygenation of the sulfoxy bridge of the cycloadducts with PBr3.

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Bibliographic Details
Published in:Journal of chemical research 2009-11, Vol.2009 (11), p.702-704
Main Authors: Li, Yuan-Qiang, Thiemann, Carolin, Ohira, Daisuke, Mataka, Shuntaro, Tashiro, Masashi, Thiemann, Thies
Format: Article
Language:English
Subjects:
Alkenes
Cycloaddition
Deoxygenation
Thiophenes
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Description
Summary:Oligocycles with a 7-thiabicyclo[2.2.1]hept-5-ene unit have been prepared stereoselectively by cycloaddition of thiophene S-oxides to alkenes and subsequent deoxygenation of the sulfoxy bridge of the cycloadducts with PBr3.
ISSN:1747-5198
2047-6507
DOI:10.3184/030823409X12562932030738