Pyrolysis study of hydrophobic tholins By TG-MS, TG, DTA and DSC methods

• Published in: Journal of thermal analysis and calorimetry 2013-03, Vol.111 (3), p.1699-1706
• Main Authors: de la Fuente, José L., Ruiz-Bermejo, Marta, Menor-Salván, César, Osuna-Esteban, Susana
• Format: Article
• Language: English
• Subjects: Acetylene; Activation; Analytical Chemistry; Atmospheres; Boron nitride; Calorimetry; Chemistry; Chemistry and Materials Science; Differential scanning calorimetry; Differential thermal analysis; Dynamical systems; Dynamics; Exact sciences and technology; Inorganic Chemistry; Inorganic chemistry and origins of life; Measurement Science and Instrumentation; Methods; Oligomers; Origins of life; Physical Chemistry; Polymer Sciences; Pyrolysis; Thermal analysis
• ISSN: 1388-6150; 1588-2926; 1572-8943
• DOI: 10.1007/s10973-011-2141-1

This study presents the thermogravimetry (TG) of hydrophobic tholins , obtained from different simulation experiments of prebiotic synthesis carried out in a CH 4 /N 2 /H 2 atmosphere with spark discharge activation of aqueous aerosols and liquid water. Differential thermal analysis and differential scanning calorimetry were also used to evaluate the thermal behaviour of these complex organic compounds that could play an important role in prebiotic chemistry. A coupled thermogravimetry-mass spectrometry system allowed us to analyse the principal volatile thermal decomposition and fragmentation products of the hydrophobic tholins under dynamic conditions and an inert atmosphere. During their thermal degradation, which occurs in two stages, a wide variety of hydrocarbon products including methane, vinyl monomers (such as ethylene and propylene), acetylene, oligomers, and some other unknown compounds are found. Besides, a thermally stable structure is present (graphitic structure) in these particular organic substances. Finally, data collected from TG experiments in an oxidative atmosphere showed significant differences at temperatures above 240 °C. According to these results, the different techniques of thermal analysis here applied have proved to be an adequate methodology for the study and characterization of these complex systems, structures of which remain controversial even in these days.