2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents

Stable and easy-to-handle zwitterions containing carbanion and pyridinium moieties were synthesized, and their structural studies by both X-ray crystallography and theoretical methods revealed the stereoelectronic effect in the zwitterionic 'C(-)-C-N(+)' system.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-10, Vol.49 (86), p.10091-10093
Main Authors: Yanai, Hikaru, Takahashi, Yoichi, Fukaya, Haruhiko, Dobashi, Yasuo, Matsumoto, Takashi
Format: Article
Language:English
Subjects:
Crystallography, X-Ray
Drug Stability
Ions
Molecular Structure
Pyridinium Compounds - chemical synthesis
Pyridinium Compounds - chemistry
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Description
Summary:Stable and easy-to-handle zwitterions containing carbanion and pyridinium moieties were synthesized, and their structural studies by both X-ray crystallography and theoretical methods revealed the stereoelectronic effect in the zwitterionic 'C(-)-C-N(+)' system.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc46171h