Highly enantioselective iron(II)-catalyzed opening reaction of aromatic meso-epoxides with indoles

A highly enantioselective method for the catalytic cis-stilbene oxide opening reaction with indole derivatives was developed. The scope of the reaction was studied with a selection of aromatic meso-epoxides and various indoles, and the desired 2-(indol-3-yl)ethanol derivatives were obtained in good...

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Published in:Organic & biomolecular chemistry 2013-11, Vol.11 (43), p.7463-7466
Main Authors: Plancq, Baptiste, Lafantaisie, Mathieu, Companys, Simon, Maroun, Cendrella, Ollevier, Thierry
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Language:English
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cited_by cdi_FETCH-LOGICAL-c287t-9ca99e6f862b9617e308ac1532138324d2329ff328db0793c31aea5dd40ad3633
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creator Plancq, Baptiste
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description A highly enantioselective method for the catalytic cis-stilbene oxide opening reaction with indole derivatives was developed. The scope of the reaction was studied with a selection of aromatic meso-epoxides and various indoles, and the desired 2-(indol-3-yl)ethanol derivatives were obtained in good to excellent yields with excellent enantioselectivities (from 96 to >99% ee).
doi_str_mv 10.1039/c3ob41782d
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title Highly enantioselective iron(II)-catalyzed opening reaction of aromatic meso-epoxides with indoles
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