Design and Synthesis of Two Porous Metal–Organic Frameworks with nbo and agw Topologies Showing High CO2 Adsorption Capacity

Two novel porous copper-based metal–organic frameworks with nbo and agw topologies have been designed and synthesized using tetracarboxylate and tricarboxylate ligands, respectively. They possess large surface areas and high CO2 adsorption capacities (up to 170 cm3/g or 7.59 mmol/g at 0 °C under amb...

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Bibliographic Details
Published in:Inorganic chemistry 2013-10, Vol.52 (19), p.10720-10722
Main Authors: Liang, Zhiqiang, Du, Jingjing, Sun, Libo, Xu, Jin, Mu, Ying, Li, Yi, Yu, Jihong, Xu, Ruren
Format: Article
Language:English
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Summary:Two novel porous copper-based metal–organic frameworks with nbo and agw topologies have been designed and synthesized using tetracarboxylate and tricarboxylate ligands, respectively. They possess large surface areas and high CO2 adsorption capacities (up to 170 cm3/g or 7.59 mmol/g at 0 °C under ambient pressure).
ISSN:0020-1669
1520-510X
DOI:10.1021/ic4017189