A functionalized MIL-101(Cr) metal-organic framework for enhanced hydrogen release from ammonia borane at low temperature

Hydrogen released from ammonia borane in MIL-101(Cr) can be significantly improved by the attached amino and amide groups. The release with minimum impurities starts at 68 °C, reaching 1.6 equivalent of ammonia borane at 85 °C for the amino modified MOFs (NH2-MIL-101).

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-11, Vol.49 (90), p.10629-10631
Main Authors: Gao, Liang, Li, Chi-Ying Vanessa, Yung, Hoi, Chan, Kwong-Yu
Format: Article
Language:English
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Summary:Hydrogen released from ammonia borane in MIL-101(Cr) can be significantly improved by the attached amino and amide groups. The release with minimum impurities starts at 68 °C, reaching 1.6 equivalent of ammonia borane at 85 °C for the amino modified MOFs (NH2-MIL-101).
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc45719b