Dehydrogenative Heck Reaction (Fujiwara-Moritani Reaction) of Unactivated Olefins with Simple Dihydropyrans under Aprotic Conditions

The dehydrogenative Heck coupling (Fujiwara–Moritani reaction) of unactivated olefins with 3,4‐dihydro‐2H‐pyrans is described. The two main highlights of the work are the use of unconventional unactivated olefins as coupling partners in the palladium‐catalyzed reaction and the use of aprotic conditi...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2013-08, Vol.355 (11-12), p.2185-2190
Main Authors: Pawar, Govind Goroba, Singh, Gaurav, Tiwari, Virendra Kumar, Kapur, Manmohan
Format: Article
Language:English
Subjects:
alkenylation
Catalysis
CH activation
Dehydrogenation
dehydrogenative Heck reaction
dihydropyrans
Fujiwara-Moritani reaction
Joining
Olefins
Synthesis
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Summary:The dehydrogenative Heck coupling (Fujiwara–Moritani reaction) of unactivated olefins with 3,4‐dihydro‐2H‐pyrans is described. The two main highlights of the work are the use of unconventional unactivated olefins as coupling partners in the palladium‐catalyzed reaction and the use of aprotic conditions for the coupling reaction of the acid‐labile dihydropyrans.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201300370