Microwave-Assisted Solvothermal Synthesis and Optical Properties of Tagged MIL-140A Metal–Organic Frameworks

A series of tagged MIL-140A-R frameworks have been synthesized using a microwave-assisted solvothermal method. Compared with their UiO-66-R polymorphs, the absorption energies in the MIL-140A-R series (R = NH2, NO2, Br, Cl, and F) are extended toward the visible region because of the spatial arrange...

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Bibliographic Details
Published in:Inorganic chemistry 2013-11, Vol.52 (22), p.12878-12880
Main Authors: Liang, Weibin, Babarao, Ravichandar, D’Alessandro, Deanna M
Format: Article
Language:English
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Summary:A series of tagged MIL-140A-R frameworks have been synthesized using a microwave-assisted solvothermal method. Compared with their UiO-66-R polymorphs, the absorption energies in the MIL-140A-R series (R = NH2, NO2, Br, Cl, and F) are extended toward the visible region because of the spatial arrangement of the linkers.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic4024234