A new versatile approach to synthesise enantioenriched 3-hydroxyoxindoles, 1,3-dihydroisobenzofuran and 3-isochromanone derivatives by a rhodium-catalyzed asymmetric arylation-cyclization sequence

A novel arylation-cyclization strategy for the highly enantioselective synthesis of titled heterocycles with a quaternary stereogenic center has been developed.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-12, Vol.49 (99), p.11659-11661
Main Authors: Li, Yi, Zhu, Dong-Xing, Xu, Ming-Hua
Format: Article
Language:English
Subjects:
Benzofurans - chemical synthesis
Benzofurans - chemistry
Catalysis
Chromones - chemical synthesis
Chromones - chemistry
Cyclization
Indoles - chemical synthesis
Indoles - chemistry
Rhodium - chemistry
Stereoisomerism
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Description
Summary:A novel arylation-cyclization strategy for the highly enantioselective synthesis of titled heterocycles with a quaternary stereogenic center has been developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc47927g