Tight ceramic UF membrane as RO pre-treatment: The role of electrostatic interactions on phosphate rejection

• Published in: Water research (Oxford) 2014-01, Vol.48, p.498-507
• Main Authors: Shang, Ran, Verliefde, Arne R.D., Hu, Jingyi, Zeng, Zheyi, Lu, Jie, Kemperman, Antoine J.B., Deng, Huiping, Nijmeijer, Kitty, Heijman, Sebastiaan G.J., Rietveld, Luuk C.
• Format: Article
• Language: English
• Subjects: Applied sciences; Biofouling; Ceramic membrane; Ceramics; Chemical engineering; Donnan exclusion; Electrostatic repulsion; Exact sciences and technology; Membrane separation (reverse osmosis, dialysis...); Membranes, Artificial; Osmosis; Phosphate limitation; Phosphate rejection; Phosphates - chemistry; Pollution; Static Electricity; Tight ultrafiltration; Ultrafiltration; Water treatment and pollution
• ISSN: 0043-1354; 1879-2448
• DOI: 10.1016/j.watres.2013.10.008

Phosphate limitation has been reported as an effective approach to inhibit biofouling in reverse osmosis (RO) systems for water purification. The rejection of dissolved phosphate by negatively charged TiO2 tight ultrafiltration (UF) membranes (1 kDa and 3 kDa) was observed. These membranes can potentially be adopted as an effective process for RO pre-treatment in order to constrain biofouling by phosphate limitation. This paper focuses on electrostatic interactions during tight UF filtration. Despite the larger pore size, the 3 kDa ceramic membrane exhibited greater phosphate rejection than the 1 kDa membrane, because the 3 kDa membrane has a greater negative surface charge and thus greater electrostatic repulsion against phosphate. The increase of pH from 6 to 8.5 led to a substantial increase in phosphate rejection by both membranes due to increased electrostatic repulsion. At pH 8.5, the maximum phosphate rejections achieved by the 1 kDa and 3 kDa membrane were 75% and 86%, respectively. A Debye ratio (ratio of the Debye length to the pore radius) is introduced in order to evaluate double layer overlapping in tight UF membranes. Threshold Debye ratios were determined as 2 and 1 for the 1 kDa and 3 kDa membranes, respectively. A Debye ratio below the threshold Debye ratio leads to dramatically decreased phosphate rejection by tight UF membranes. The phosphate rejection by the tight UF, in combination with chemical phosphate removal by coagulation, might accomplish phosphate-limited conditions for biological growth and thus prevent biofouling in the RO systems. [Display omitted] •Negative-charged tight UF membrane can reject low-diffusive anion, e.g. phosphate.•An essential gauge for this anion rejection by tight UF is threshold Debye ratio.•Electrostatic repulsion & Donnan exclusion govern the anion rejection by tight UF.•Surface charge significantly impacts the rejection rate of phosphate by tight UF.