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Tuning Omniphobicity via Morphological Control of Metal–Organic Framework Functionalized Surfaces
Fabrication of microstructures for imparting omniphobicity to a surface generally requires the use of lithographic techniques and specialized equipment. We report instead a simple strategy for the synthesis of microstructured surfaces via metal–organic framework (MOF) self-assembly. Our method allow...
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| Published in: | Journal of the American Chemical Society 2013-11, Vol.135 (44), p.16272-16275 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-a315t-e08bcae47d0ecb233c1d9d90c8953caff4eb092b05538f022729f9ad2979f7e63 |
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| cites | cdi_FETCH-LOGICAL-a315t-e08bcae47d0ecb233c1d9d90c8953caff4eb092b05538f022729f9ad2979f7e63 |
| container_end_page | 16275 |
| container_issue | 44 |
| container_start_page | 16272 |
| container_title | Journal of the American Chemical Society |
| container_volume | 135 |
| creator | Tan, Tristan T. Y Reithofer, Michael R Chen, Eric Y Menon, Ajay G Hor, T. S. Andy Xu, Jianwei Chin, Jia Min |
| description | Fabrication of microstructures for imparting omniphobicity to a surface generally requires the use of lithographic techniques and specialized equipment. We report instead a simple strategy for the synthesis of microstructured surfaces via metal–organic framework (MOF) self-assembly. Our method allows us to localize epitaxial growth of MOF at the tips of needle crystals to create mushroom-shaped structures, thus conferring re-entrant textures to the MOF-functionalized surfaces. These structures synthesized via wet chemistry were found to have omniphobic properties due to the resulting re-entrant texture. |
| doi_str_mv | 10.1021/ja407896m |
| format | article |
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| ispartof | Journal of the American Chemical Society, 2013-11, Vol.135 (44), p.16272-16275 |
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| language | eng |
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| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| subjects | Hydrophobic and Hydrophilic Interactions Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Particle Size Surface Properties |
| title | Tuning Omniphobicity via Morphological Control of Metal–Organic Framework Functionalized Surfaces |
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