Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

Monomeric (amino)(carboxy) radicals were synthesized in two steps: the addition of a stable cyclic (alkyl)(amino) carbene to an acyl chloride, followed by a one-electron reduction. Their stability toward dimerization also allows for the synthesis of related bi- and triradicals.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2013-12, Vol.135 (50), p.18766-18769
Main Authors: Mahoney, Janell K, Martin, David, Moore, Curtis E, Rheingold, Arnold L, Bertrand, Guy
Format: Article
Language:English
Subjects:
Cyclization
Free Radicals
Methane - analogs & derivatives
Methane - chemistry
Models, Molecular
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Description
Summary:Monomeric (amino)(carboxy) radicals were synthesized in two steps: the addition of a stable cyclic (alkyl)(amino) carbene to an acyl chloride, followed by a one-electron reduction. Their stability toward dimerization also allows for the synthesis of related bi- and triradicals.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja4104765