Kinetic Modeling of Methane Hydrate Formation in the Presence of Low-Dosage Water-Soluble Ionic Liquids

• Published in: Chemical engineering & technology 2013-11, Vol.36 (11), p.1915-1923
• Main Authors: Nazari, K., Moradi, M. R., Ahmadi, A. N.
• Format: Article
• Language: English
• Subjects: Gas hydrates; Inhibition; Ionic liquids; Kinetic modeling; Methane hydrate formation
• ISSN: 0930-7516; 1521-4125
• DOI: 10.1002/ceat.201300285

The kinetic and thermodynamic effects of three typical low‐dosage imidazolium‐based ionic liquids (ILs) on methane hydrate formation and dissociation were investigated, considering the anion nature and subcooling and/or overpressure driving forces. Isochoric hydrate formation and dissociation data were obtained by the modified slow step‐heating method. ILs proved to have a dual effect on both formation and dissociation of methane hydrate including thermodynamic and kinetic inhibition. Kinetic modeling of methane hydrate inhibition by low‐dosage ILs was performed. Kinetic analysis showed that IL inhibitors mainly cause a delay in the nucleation or hydrate growth step. The related inhibition mechanism was resolved regarding the ionic nature and electrostatic interactions of ILs with water molecules. Two binomial exponential kinetic relations were derived and used for simple methane hydrate formation in the presence of ILs as kinetic hydrate inhibitors. The proposed relations can serve for a quick estimation of the nature, extent, strength, and effectiveness of ILs on various gas hydrates. Due to the risks of hydrates in industrial processes, precise knowledge of kinetics of hydrate formation/dissociation and applying reliable models is a priority. Kinetic modeling and inhibition of gas hydrate formation in the presence of imidazolium‐based ionic liquids are described. The proposed kinetic relations can serve for a quick estimation of the effects of ILs on gas hydrates.