Study of Intermolecular Interactions in the Corrole Matrix by Solid-State NMR under 100 kHz MAS and Theoretical Calculations

A combination of solid‐state NMR techniques and theoretical calculations confirmed that unsubstituted metal‐free corroles form supramolecular systems with toluene through π–π interactions in the solid state. Ultrafast magic angle spinning (MAS) enabled the use of 1H–1H homonuclear correlation spectr...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2013-12, Vol.52 (52), p.14108-14111
Main Authors: Kobayashi, Takeshi, Mao, Kanmi, Paluch, Piotr, Nowak-Król, Agnieszka, Sniechowska, Justyna, Nishiyama, Yusuke, Gryko, Daniel T., Potrzebowski, Marek J., Pruski, Marek
Format: Article
Language:English
Subjects:
corroles
host-guest interactions
solid-state NMR spectroscopy
theoretical calculations
ultrafast MAS
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A combination of solid‐state NMR techniques and theoretical calculations confirmed that unsubstituted metal‐free corroles form supramolecular systems with toluene through π–π interactions in the solid state. Ultrafast magic angle spinning (MAS) enabled the use of 1H–1H homonuclear correlation spectroscopy to explore those intermolecular interactions for which heteronuclear correlation methods were difficult to apply.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201305475