Oxidative deprotection of tetrahydropyranyl and trimethylsilyl ethers in water using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride under neutral conditions

The oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers in water using 1,4-dichloro-1,4-diazonia-bicyclo[2,2,2]octane bis-chloride as a new efficient reagent under neutral conditions is described. The DABCO was regenerated, rechlorinated and reused several times.

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Bibliographic Details
Published in:Journal of chemical research 2007-05, Vol.2007 (5), p.259-262
Main Authors: Tajbakhsh, Mahmood, Habibzadeh, Setareh
Format: Article
Language:English
Subjects:
Ethers
Online Access:Get full text
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Description
Summary:The oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers in water using 1,4-dichloro-1,4-diazonia-bicyclo[2,2,2]octane bis-chloride as a new efficient reagent under neutral conditions is described. The DABCO was regenerated, rechlorinated and reused several times.
ISSN:1747-5198
2047-6507
DOI:10.3184/030823407X209723