An Odorless, One-Pot Synthesis of Thioesters from Organic Halides, Thiourea and Benzoyl Chlorides in Water

Thioesterification can be realized via an odorless, one‐pot reaction through the in situ generation of S‐alkylisothiouronium salts from organic halides and thiourea in aqueous Triton X‐100 (TX100) micelles. The protocol is free of foul‐smell thiols and organic solvents, and operates under mild condi...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2013-05, Vol.355 (7), p.1271-1276
Main Authors: Lu, Guo-ping, Cai, Chun
Format: Article
Language:English
Subjects:
Catalysis
green chemistry
micelles
multicomponent reactions
S-alkylisothiouronium salts
thioesterification
water chemistry
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Summary:Thioesterification can be realized via an odorless, one‐pot reaction through the in situ generation of S‐alkylisothiouronium salts from organic halides and thiourea in aqueous Triton X‐100 (TX100) micelles. The protocol is free of foul‐smell thiols and organic solvents, and operates under mild conditions, thereby offering considerable potential for applications in organic synthesis.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201201059