Triarylaminium Salt-Initiated Aerobic Double Friedel-Crafts Reaction of Glycine Derivatives with Indoles

A novel and efficient stable radical cation triarylaminium salt‐catalyzed aerobic double Friedel–Crafts alkylation reaction of glycine derivatives with indoles has been developed. The reaction was performed in the absence of any other additives under mild conditions and only requires an air atmosphe...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2013-07, Vol.355 (10), p.1911-1916
Main Authors: Huo, Congde, Wang, Cheng, Sun, Chougu, Jia, Xiaodong, Wang, Xicun, Chang, Wenju, Wu, Mingxia
Format: Article
Language:English
Subjects:
aerobic conditions
Alkylation
Friedel-Crafts alkylation
glycine derivatives
indoles
triarylaminium salts
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Summary:A novel and efficient stable radical cation triarylaminium salt‐catalyzed aerobic double Friedel–Crafts alkylation reaction of glycine derivatives with indoles has been developed. The reaction was performed in the absence of any other additives under mild conditions and only requires an air atmosphere (or oxygen, 1 atm) as co‐oxidant.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201300276