Triarylaminium Salt-Initiated Aerobic Double Friedel-Crafts Reaction of Glycine Derivatives with Indoles

A novel and efficient stable radical cation triarylaminium salt‐catalyzed aerobic double Friedel–Crafts alkylation reaction of glycine derivatives with indoles has been developed. The reaction was performed in the absence of any other additives under mild conditions and only requires an air atmosphe...

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Published in:Advanced synthesis & catalysis 2013-07, Vol.355 (10), p.1911-1916
Main Authors: Huo, Congde, Wang, Cheng, Sun, Chougu, Jia, Xiaodong, Wang, Xicun, Chang, Wenju, Wu, Mingxia
Format: Article
Language:English
Subjects:
aerobic conditions
Alkylation
Friedel-Crafts alkylation
glycine derivatives
indoles
triarylaminium salts
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cited_by cdi_FETCH-LOGICAL-c3976-212e6f308be16ba7c0ee6abaa36994811b3577ebc6716124c9e2c3840001ad83
cites cdi_FETCH-LOGICAL-c3976-212e6f308be16ba7c0ee6abaa36994811b3577ebc6716124c9e2c3840001ad83
container_end_page 1916
container_issue 10
container_start_page 1911
container_title Advanced synthesis & catalysis
container_volume 355
creator Huo, Congde
Wang, Cheng
Sun, Chougu
Jia, Xiaodong
Wang, Xicun
Chang, Wenju
Wu, Mingxia
description A novel and efficient stable radical cation triarylaminium salt‐catalyzed aerobic double Friedel–Crafts alkylation reaction of glycine derivatives with indoles has been developed. The reaction was performed in the absence of any other additives under mild conditions and only requires an air atmosphere (or oxygen, 1 atm) as co‐oxidant.
doi_str_mv 10.1002/adsc.201300276
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subjects aerobic conditions
Alkylation
Friedel-Crafts alkylation
glycine derivatives
indoles
triarylaminium salts
title Triarylaminium Salt-Initiated Aerobic Double Friedel-Crafts Reaction of Glycine Derivatives with Indoles
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