Recent Advances in Catalytic Asymmetric Decarboxylative Addition Reactions

This review examines recent advances in asymmetric catalytic decarboxylative addition reactions which have become a powerful method to form CC and CX bond using relatively cheap and stable carboxylic compounds. In these reactions, new CC or CX bonds are formed with extrusion of carbon dioxide (C...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2013-10, Vol.355 (14-15), p.2745-2755
Main Author: Wang, Zu-Li
Format: Article
Language:English
Subjects:
addition reactions
asymmetric catalysis
Asymmetry
Bonding
Carbon dioxide
Carboxylic acids
Catalysis
Catalysts
CC bond formation
decarboxylation
Extrusion
Synthesis
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Summary:This review examines recent advances in asymmetric catalytic decarboxylative addition reactions which have become a powerful method to form CC and CX bond using relatively cheap and stable carboxylic compounds. In these reactions, new CC or CX bonds are formed with extrusion of carbon dioxide (CO2). Asymmetric decarboxylative addition reactions have become alternatives to traditional addition reactions. Various asymmetric reactions between carboxylic acids and unsaturated compounds are summarized. The challenges and opportunities of these reactions are discussed.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201300375