Synthesis of Functionalized Bicyclic Imines via Intramolecular Azide-Alkene 1,3-Dipolar Cycloaddition/Intramolecular Stork Alkylation Cascade Reaction

A cascade intramolecular azide‐alkene 1,3‐dipolar cycloaddition/Stork alkylation reaction has been developed for the synthesis of functionalized cyclic imines with a pyrroline and piperideine structures, employing readily available ω‐azidodienes.

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2013-05, Vol.355 (7), p.1237-1242
Main Authors: de Miguel, Irene, Velado, Marina, Herradón, Bernardo, Mann, Enrique
Format: Article
Language:English
Subjects:
Alkylation
azides
cycloaddition
piperideines
pyrrolines
Stork alkylation
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Description
Summary:A cascade intramolecular azide‐alkene 1,3‐dipolar cycloaddition/Stork alkylation reaction has been developed for the synthesis of functionalized cyclic imines with a pyrroline and piperideine structures, employing readily available ω‐azidodienes.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201201027