The Reaction of Tertiary Anilines with Maleimides under Visible Light Redox Catalysis

Tertiary anilines can be prompted to react with N‐aryl‐ and N‐benzylmaleimides to form tetrahydroquinoline products under photocatalysis using visible light irradiation, the ruthenium or iridium complexes Ru(bpy)3Cl2 or Ir(ppy)2(dtbbpy)PF6 as catalyst, and air as terminal oxidant.

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2012-12, Vol.354 (18), p.3561-3567
Main Authors: Ju, Xuhui, Li, Dianjun, Li, Weifei, Yu, Wei, Bian, Fengling
Format: Article
Language:English
Subjects:
aerobic oxidation
Aniline
maleimides
photocatalysis
tertiary anilines
tetrahydroquinolines
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Description
Summary:Tertiary anilines can be prompted to react with N‐aryl‐ and N‐benzylmaleimides to form tetrahydroquinoline products under photocatalysis using visible light irradiation, the ruthenium or iridium complexes Ru(bpy)3Cl2 or Ir(ppy)2(dtbbpy)PF6 as catalyst, and air as terminal oxidant.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201200608