Synthesis and crystal structure of the chiral-linked tetrahedral cluster [(μ 3 -Se)RuCo 2 (CO) 8 ] 2 (DIOP)

The new chiral Ru-Co mixed-metal linked tetrahedral cluster [(?3-Se)RuCo2(CO)8]2(DIOP) 3 has been synthesised from reaction between (?3-Se)RuCo2(CO)9 1 and the (-)-DIOP [ 2 (2,2-dimethyl-1,3-dioxolane-4,5-diylbis-methylene) bisdiphenylphosphine] diphosphine compound. The structure of cluster 3 has b...

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Bibliographic Details
Published in:Journal of chemical research 2004-11, Vol.2004 (11), p.756-757
Main Authors: Zhu, Bao-Hua, Hong, Hong, Yin, Yuan-Qi, Sun, Jie
Format: Article
Language:English
Subjects:
Clusters
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Summary:The new chiral Ru-Co mixed-metal linked tetrahedral cluster [(?3-Se)RuCo2(CO)8]2(DIOP) 3 has been synthesised from reaction between (?3-Se)RuCo2(CO)9 1 and the (-)-DIOP [ 2 (2,2-dimethyl-1,3-dioxolane-4,5-diylbis-methylene) bisdiphenylphosphine] diphosphine compound. The structure of cluster 3 has been established by single-crystal X-ray diffraction method.
ISSN:1747-5198
2047-6507
DOI:10.3184/0308234043431492