Magnetic and structural studies of the multifunctional material SrFe(0.75)Mo(0.25)O(3-δ)

• Published in: Inorganic chemistry 2012-11, Vol.51 (22), p.12273-12280
• Main Authors: Retuerto, M, Li, M-R, Go, Y B, Ignatov, A, Croft, M, Ramanujachary, K V, Hadermann, J, Hodges, J P, Herber, R H, Nowik, I, Greenblatt, M
• Format: Article
• Language: English
• ISSN: 1520-510X
• DOI: 10.1021/ic301550m

SrFe0.75Mo0.25O3-δ has been recently discovered as an extremely efficient electrode for intermediate temperature solid oxide fuel cells (IT-SOFCs). We have performed structural and magnetic studies to fully characterize this multifunctional material. We have observed by powder neutron diffraction (PND) and transmission electron microscopy (TEM) that its crystal symmetry is better explained with a tetragonal symmetry (I4/mcm space group) than with the previously reported orthorhombic symmetry (Pnma space group). The temperature dependent magnetic properties indicate an exceptionally high magnetic ordering temperature (TN ∼ 750 K), well above room temperature. The ordered magnetic structure at low temperature was determined by PND to be an antiferromagnetic coupling of the Fe cations. Mössbauer spectroscopy corroborated the PND results. A detailed study, with X-ray absorption spectroscopy (XAS), in agreement with the Mössbauer results, confirmed the formal oxidation states of the cations to be mixed valence Fe(3+/4+) and Mo(6+).