The luminescence properties of linear vs. kinked aurophilic 1-D chains of bis(dithiocarbamato)gold(I) dimers

Widely varying luminescence spectra are reported for 1-D chains of bis(dithiocarbamato)gold(I) dimers. Variable pressure luminescence spectra elucidate the effect of angular overlap on the emission properties of the aurophilic chain.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (24), p.3148-3150
Main Authors: Roberts, Ryan J, Bélanger-Desmarais, Nicolas, Reber, Christian, Leznoff, Daniel B
Format: Article
Language:English
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Summary:Widely varying luminescence spectra are reported for 1-D chains of bis(dithiocarbamato)gold(I) dimers. Variable pressure luminescence spectra elucidate the effect of angular overlap on the emission properties of the aurophilic chain.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc47944g