A disk-aromatic bowl cluster B sub(30): toward formation of boron buckyballs

The B sub(30) boron cluster has a bowl rather than a double-ring or a triple-ring tubular structure. This bowl isomer exhibits disk-aromaticity similar to that found for B sub(20) super(2-) and B sub(19) super(-) clusters. We confirmed that the concept of disk-aromaticity can be applied to both plan...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (13), p.1558-1560
Main Authors: Tai, Truong Ba, Duong, Long Van, Pham, Hung Tan, Mai, Dang Thi Tuyet, Nguyen, Minh Tho
Format: Article
Language:English
Subjects:
Boron
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The B sub(30) boron cluster has a bowl rather than a double-ring or a triple-ring tubular structure. This bowl isomer exhibits disk-aromaticity similar to that found for B sub(20) super(2-) and B sub(19) super(-) clusters. We confirmed that the concept of disk-aromaticity can be applied to both planar and non-planar systems.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48392d