Novel silicon-modified phenolic novolacs and their biofiber-reinforced composites: Preparation, characterization and performance

4,4′-(1,3-Dipropyl-tetramethyldisiloxane)bis-2-methoxyphenol (SIE), a novel silicone-contained biphenol type monomer, is synthesized from eugenol and 1,1,3,3-tetramethyldisiloxane, and used to modify phenolic novolac through copolymerization with phenol and formaldehyde to yield SIE-modified resins...

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Published in:Composites science and technology 2013-10, Vol.87, p.189-195
Main Authors: Li, Cheng, Fan, Hong, Wang, De-Yi, Hu, Jijiang, Wan, Jintao, Li, Bogeng
Format: Article
Language:English
Subjects:
A. Polymer–matrix composites
Applied sciences
B. Curing
B. Electrical properties
Composites
Copolymerization
D. DMTA
D. DSC
Exact sciences and technology
Forms of application and semi-finished materials
Monomers
Novolacs
Polymer industry, paints, wood
Polymer matrix composites
Polymers
Resins
Silicones
Sisal
Technology of polymers
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cited_by cdi_FETCH-LOGICAL-c458t-5baebcb446750fc5ad01a2d8df6fd78a683bd8f044318f3a919a6d4802508d5e3
cites cdi_FETCH-LOGICAL-c458t-5baebcb446750fc5ad01a2d8df6fd78a683bd8f044318f3a919a6d4802508d5e3
container_end_page 195
container_issue
container_start_page 189
container_title Composites science and technology
container_volume 87
creator Li, Cheng
Fan, Hong
Wang, De-Yi
Hu, Jijiang
Wan, Jintao
Li, Bogeng
description 4,4′-(1,3-Dipropyl-tetramethyldisiloxane)bis-2-methoxyphenol (SIE), a novel silicone-contained biphenol type monomer, is synthesized from eugenol and 1,1,3,3-tetramethyldisiloxane, and used to modify phenolic novolac through copolymerization with phenol and formaldehyde to yield SIE-modified resins (SPNs). Then, the SPNs are used as resin matrix, while surface-treated chopped sisal fiber is used as the reinforced filler to produce the novel phenolic molding composites. Eugenol and sisal are biobased renewable materials. Due to modification of SIE, the ultimate composites expressed excellent electrical resistance, low water absorption and high thermal stability compared to the normal composites. Our work provides a facile and effective way to prepare the silicone modified, biofiber-reinforced phenolic composites with improved water resistance and electric property.
doi_str_mv 10.1016/j.compscitech.2013.08.016
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1879-1050
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subjects A. Polymer–matrix composites
Applied sciences
B. Curing
B. Electrical properties
Composites
Copolymerization
D. DMTA
D. DSC
Exact sciences and technology
Forms of application and semi-finished materials
Monomers
Novolacs
Polymer industry, paints, wood
Polymer matrix composites
Polymers
Resins
Silicones
Sisal
Technology of polymers
title Novel silicon-modified phenolic novolacs and their biofiber-reinforced composites: Preparation, characterization and performance
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