A New 6-Connected Ni(II) Complex With 5-methylisophthalic Acid: Synthesis, Crystal Structure, and Properties

A new Ni(II) metal-organic coordination polymer, {[Ni(mip) (1,6-bth)(H 2 O)]·H 2 O} n (1), (H 2 mip = 5-methylisophthalic acid, 1,6-bth = 1,6-bis(1,2,4-triazol-1-yl)hexane), was assembled under hydrothermal condition by the reactions of Ni(II) acetate with H 2 mip and 1,6-bth. Compound 1 was charact...

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Bibliographic Details
Published in:Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry metal-organic, and nano-metal chemistry, 2013-03, Vol.43 (3), p.279-282
Main Authors: Chang, Xin-Hong, Sun, Xiao-Yuan
Format: Article
Language:English
Subjects:
4-triazol-1-yl)hexane
5-methylisophthalic acid
6-bis
Crystal structure
Ni(II) complex
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Summary:A new Ni(II) metal-organic coordination polymer, {[Ni(mip) (1,6-bth)(H 2 O)]·H 2 O} n (1), (H 2 mip = 5-methylisophthalic acid, 1,6-bth = 1,6-bis(1,2,4-triazol-1-yl)hexane), was assembled under hydrothermal condition by the reactions of Ni(II) acetate with H 2 mip and 1,6-bth. Compound 1 was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. The results reveal that compound 1 consists of mip anion-bridged 1D Ni II chains that are linked by 1,6-bth into a 2D layer. In addition, the thermal stability of 1 was briefly investigated.
ISSN:1553-3174
1553-3182
DOI:10.1080/15533174.2012.740721