Upgrading and extraction of bitumen from Nigerian tar sand by supercritical carbon dioxide

• Published in: Applied energy 2014-01, Vol.113, p.1397-1404
• Main Authors: Rudyk, Svetlana, Spirov, Pavel
• Format: Article
• Language: English
• Subjects: Applied sciences; Asphaltenes; Biomarkers; Bitumen upgrading; Bitumens; Carbon dioxide; Crude oil, natural gas and petroleum products; Energy; Exact sciences and technology; Extraction; Fuels; Processing of crude oil and oils from shales and tar sands. Processes. Equipment. Refinery and treatment units; Recovery; Tar sand; Tar sands; Upgrading
• ISSN: 0306-2619; 1872-9118
• DOI: 10.1016/j.apenergy.2013.08.076

[Display omitted] •Bitumen extraction from tar sand by liquid carbon dioxide method was investigated.•Greatest recovery of 29.6% was obtained at 50MPa with the addition of salty water.•Upgraded bitumen was clean of asphaltenes and petcokes. The current experimental study describes the recovery of bitumen from Nigerian tar sand by the supercritical carbon dioxide method, which has the advantages of a substantial reduction in water consumption, an absence of chemicals, and an upgrading of the bitumen through the rejection of solids, petcokes and asphaltenes. The bitumen extraction from 50g piece of tar sand was carried out at 50, 60 and 65MPa and 110°C by pure carbon dioxide and with the addition of 10mL of fresh or salty water. The recovery decreased in the following order: with salty water, with fresh water, pure CO2. The maximum recovery of 29.6% was obtained at 50MPa with the addition of salty water declining at higher pressures. The heaviest fractions were extracted by pure carbon dioxide at 60 and 65MPa. The presence of bisnorhopane, a biomarker typical for source rocks formed in marine depositional environment, was detected in crude bitumen and all extracts by GC–MS TIC analysis.