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Friedel–Crafts Bottom-up Synthesis of Fluorene-Based Soluble Luminescent Organic Nanogrids
A series of fluorene-based grid molecules (so-called Grid fluorenes) have been synthesized by means of shape-supported cyclization, starting from H-shaped precursors via the alternative Friedel–Crafts reactions of fluorenols and Suzuki cross-coupling reactions with key cyclization yields up to 26%....
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Published in: | Organic letters 2014-03, Vol.16 (6), p.1748-1751 |
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Language: | English |
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container_end_page | 1751 |
container_issue | 6 |
container_start_page | 1748 |
container_title | Organic letters |
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creator | Wang, Long Zhang, Guang-Wei Ou, Chang-Jin Xie, Ling-Hai Lin, Jin-Yi Liu, Yu-Yu Huang, Wei |
description | A series of fluorene-based grid molecules (so-called Grid fluorenes) have been synthesized by means of shape-supported cyclization, starting from H-shaped precursors via the alternative Friedel–Crafts reactions of fluorenols and Suzuki cross-coupling reactions with key cyclization yields up to 26%. Fluorenol approaches and nanogrids open a door to soluble one-, two-, or three-dimensional nanoporous polymers as next-generation polymer mechano-semiconductors facing a new era of consciousness. |
doi_str_mv | 10.1021/ol500439z |
format | article |
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title | Friedel–Crafts Bottom-up Synthesis of Fluorene-Based Soluble Luminescent Organic Nanogrids |
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