Optimization of biodiesel production from palm oil under supercritical ethanol conditions using hexane as co-solvent: A response surface methodology approach

In the present work, response surface methodology (RSM) was used to optimize the biodiesel production from palm oil under supercritical ethanol conditions. Hexane was added as a co-solvent, which in turn accelerated the reaction rate and increased the biodiesel yield. This process enables simultaneo...

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Bibliographic Details
Published in:Fuel (Guildford) 2013-05, Vol.107, p.633-640
Main Authors: MUPPANENI, Tapaswy, REDDY, Harvind K, PONNUSAMY, Sundaravadivelnathan, PATIL, Prafulla D, YINGQIANG SUN, DAILEY, Peter, SHUGUANG DENG
Format: Article
Language:English
Subjects:
Applied sciences
Biodiesel
Energy
Energy. Thermal use of fuels
Ethanol
Ethyl alcohol
Exact sciences and technology
Fatty acids
Fuels
Palm oil
Reaction time
Response surface methodology
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Summary:In the present work, response surface methodology (RSM) was used to optimize the biodiesel production from palm oil under supercritical ethanol conditions. Hexane was added as a co-solvent, which in turn accelerated the reaction rate and increased the biodiesel yield. This process enables simultaneous transe-sterification of triglycerides and ethyl esterification of fatty acids in a shorter reaction time and may reduce the energy consumption due to simplified separation and purification steps. Different process parameters including alcohol to oil molar ratio (25:1-50:1), reaction time (10-30 min), reaction temperature (260-300 degree C) and co-solvent ratio (0.1-0.4% v/v) were optimized using response surface methodology. A mathematical model was developed for predicting the fatty acid ethyl ester (FAEE) yield. Fatty acid ethyl esters produced from palm oil were measured and analyzed using FT-IR, GC-MS and thermogravi-metric analysis (TGA) methods. The fuel properties of the biodiesel produced were determined and compared to the American society for testing and materials (ASTMs) standards for biodiesel.
ISSN:0016-2361
1873-7153
DOI:10.1016/j.fuel.2012.11.046