Spatially and temporally reconfigurable assembly of colloidal crystals

• Published in: Nature communications 2014-04, Vol.5 (1), p.3676-3676, Article 3676
• Main Authors: Kim, Youngri, Shah, Aayush A., Solomon, Michael J.
• Format: Article
• Language: English
• Subjects: 639/301/930; 639/638/298/923/916; Humanities and Social Sciences; multidisciplinary; Science; Science (multidisciplinary)
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/ncomms4676

The self-assembly of colloidal crystals is important to the production of materials with functional optical, mechanical and conductive properties. Yet, self-assembly methods are limited by their slow kinetics and lack of structural control in space and time. Refinements such as templating and directed assembly partially address the problem, albeit by introducing fixed surface features such as templates or electrodes. A template-free method to reconfigure colloidal crystals simultaneously in three-dimensional space and time would better align work in colloidal assembly with materials applications. Here, we report a photo-induced assembly method that yields regions either filled with colloidal crystals or completely devoid of colloids. The origin of the effect is found to be electrophoresis of colloids generated by photochemistry at an indium tin oxide-coated substrate. Simple optical manipulations are applied to reconfigure these assembly and depletion regions. Thus, the method represents a new kind of template-free, reconfigurable three-dimensional photolithography. Controlling colloidal assemblies without the need of a template or electrode is still a challenging goal. Here Kim et al. use photo-induced ion flow in an indium tin oxide-coated substrate to control this process, allowing reversible assembly of colloidal crystals in a three-dimensional manner.