Chiral Single-Chain Magnet: Helically Stacked [MnIII 2CuII] Triangles

The one-dimensional complex [MnIII 2CuII(μ3-O)(Cl-sao)3(EtOH)2]·EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[MnIII 3(μ3-O)Cl2(Cl-sao)3(MeOH)2(H2O)2] with [Cu(acac)2]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size eff...

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Bibliographic Details
Published in:Inorganic chemistry 2014-05, Vol.53 (9), p.4272-4274
Main Authors: Shiga, Takuya, Maruyama, Kazuya, Newton, Graham N, Inglis, Ross, Brechin, Euan K, Oshio, Hiroki
Format: Article
Language:English
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Summary:The one-dimensional complex [MnIII 2CuII(μ3-O)(Cl-sao)3(EtOH)2]·EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[MnIII 3(μ3-O)Cl2(Cl-sao)3(MeOH)2(H2O)2] with [Cu(acac)2]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic5002418