Electrical conductivity of stishovite as a function of water content

• Published in: Physics of the earth and planetary interiors 2014-02, Vol.227, p.48-54
• Main Authors: Yoshino, Takashi, Shimojuku, Akira, Li, Danyang
• Format: Article
• Language: English
• Subjects: Activation; Activation enthalpy; Al content; Aluminum oxide; Conductivity; Crusts; Electrical conductivity; Electrical resistivity; Mantle transition zone; Resistivity; Stishovite; Water
• ISSN: 0031-9201; 1872-7395
• DOI: 10.1016/j.pepi.2013.12.003

•We measured electrical conductivity of hydrous stishovite at 12GPa.•Electrical conductivity linearly increased with increasing water content.•Electrical conductivity was almost constant with Al2O3 content.•Charge carrier of aluminous stishovite is proton.•The conductivity of stishovite with 0.1wt.% H2O is equivalent to that of the mantle transition zone. The electrical conductivity of stishovite with various Al2O3 and H2O contents was measured at 12GPa of pressure (P) and temperatures (T) up to 1900K in a Kawai-type multi-anvil apparatus. Starting materials were pre-synthesized at 12GPa and 1673K from various mixtures of SiO2, Al2O3 and Al(OH)3. The synthesized stishovite aggregates contained various H2O concentrations up to 0.25wt.%. The conductivity of relatively dry stishovite was almost constant independently of Al content, whereas the conductivity significantly increased with increasing H2O content in stishovite. All electrical conductivity data fit the formula for electrical conductivity σ=σ0CWexp{-[ΔH0-αCW1/3]/kT}, where σ0 is the pre-exponential term, CW is the H2O concentration, ΔH0 is the activation enthalpy at very low H2O concentration, and k is the Boltzmann constant. The activation enthalpy decreased from 1.22 to 0.90eV with increasing H2O content from 0.01 to 0.22wt.%. A nearly linear correlation of the conductivity values on the H2O content suggests that the dominant mechanism of charge transport in stishovite is proton conduction. Although electrical conductivity of hydrous stishovite is higher than that of garnet in the subducted oceanic crust, small amount of hydrous stishovite is insufficient to raise conductivity. On the other hand, hydrous stishovite can contribute to the high conductivity occasionally observed at the mantle transition zone, if the subducted Archean continental crusts with tonalite–trondhjemite–granodiorite (TTG) composition were accumulated above the 660km seismic discontinuity.