LC Photoaligning Polymer Prepared via Selective Polymerization of Bifunctional Monomer with O-Methacryloyl and Styrene-Type Double Bonds

Phenylene-containing monomer 1 possessing O-methacryloyl and styrene double bonds with different reactivities in radical polymerization was designed as new type of bifunctional monomers suitable for preparation of LC photoaligning alkene-functionalized polymers. To elucidate an individual contributi...

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Published in:Molecular Crystals and Liquid Crystals 2014-02, Vol.590 (1), p.111-120
Main Authors: Vretik, L. O., Zagniy, V. V., Nikolaeva, O. A., Syromyatnikov, V. G.
Format: Article
Language:English
Subjects:
bifunctional monomer
Chemical bonds
Crystals
Liquid crystal photoalignment
Liquid crystal polymers
Liquid crystals
Monomers
Olefins
Photochemistry
Polymerization
Polystyrene
Radicals
Reaction kinetics
selective polymerization
Styrenes
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description Phenylene-containing monomer 1 possessing O-methacryloyl and styrene double bonds with different reactivities in radical polymerization was designed as new type of bifunctional monomers suitable for preparation of LC photoaligning alkene-functionalized polymers. To elucidate an individual contribution of double bond of each type into kinetics of bifunctional monomers polymerization, thermo- and photo-induced polymerization of model monomers were investigated and compared. Polymer poly-1 obtained by thermo-induced radical polymerization demonstrated high efficiency of LC ZLI 2293 photoalignment.
doi_str_mv 10.1080/15421406.2013.873855
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source EBSCOhost MLA International Bibliography With Full Text; Taylor and Francis Science and Technology Collection
subjects bifunctional monomer
Chemical bonds
Crystals
Liquid crystal photoalignment
Liquid crystal polymers
Liquid crystals
Monomers
Olefins
Photochemistry
Polymerization
Polystyrene
Radicals
Reaction kinetics
selective polymerization
Styrenes
title LC Photoaligning Polymer Prepared via Selective Polymerization of Bifunctional Monomer with O-Methacryloyl and Styrene-Type Double Bonds
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