A novel model electrode for investigating ion transport inside pores in an electrical double-layer capacitor: Monodispered microporous starburst carbon spheres

• Published in: Electrochimica acta 2012-10, Vol.81, p.138-148
• Main Authors: Yamada, Yuri, Sasaki, Tsuyoshi, Tatsuda, Narihito, Weingarth, Daniel, Yano, Kazuhisa, Kötz, Rüdiger
• Format: Article
• Language: English
• Subjects: Applied sciences; Capacitors; Capacitors. Resistors. Filters; Carbon; Chemistry; Electrical engineering. Electrical power engineering; Electrochemical double-layer capacitor; Electrochemical impedance spectroscopy; Electrochemistry; Electrode active material; Electrodes; Equivalence; Exact sciences and technology; General and physical chemistry; Ion transport; Monodispersed sphere; Nanocomposites; Nanomaterials; Nanoporous carbon; Nanostructure; Nyquist plots; Porosity; Surface area; Various equipment and components
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2012.07.064

► Model electrodes from monodispered microporous starburst carbon spheres. ► Defined particle diameter can be regarded as the effective pore length. ► Ion diffusion resistance accrues with increasing particle diameter. ► Contribution of electrode thickness can be separately estimated. Model electrodes were prepared from monodispered microporous starburst carbon spheres obtained by nanocasting route using monodispersed mesoporous silica spheres as a template. The obtained starburst carbon particles had different particle diameter (510–1000nm) with the same surface area of 1700m2g−1 and a pore size of 1.2nm. The effect of effective pore length, which is regarded as the particle diameter in this study, and the electrode thickness on the ion diffusive resistance of electrical double-layer capacitors has been separately investigated. Electrochemical impedance spectroscopy was employed to evaluate the length of the 45° Warburg region in the Nyquist plot, which relates to the equivalent distributed resistance in the porous structure of the electrode. For electrodes with constant thickness of 200μm an increase of the ion transport resistance was observed with increasing particle diameter. On the other hand, for constant particle diameter the resistance increases with increasing electrode thickness. Using the starburst microporous carbon spheres as electrode active materials, the contribution of the particle's micropores and of the macropores between the particles can be clearly distinguished. The influence of the effective pore length of carbon particles on the transport of ions within the pores is directly evaluated for the first time.