BF3·Et2O‑Catalyzed Formal [3 + 2] Reaction of Aziridinofullerenes with Carbonyl Compounds

The BF3·Et2O-catalyzed formal [3 + 2] reaction of aziridinofullerenes with various carbonyl compounds for the easy preparation of fullerooxazolidines has been developed. Moreover, the reaction of aziridinofullerene with ethyl formate affords the simplest fullerooxazole without substituent.

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Bibliographic Details
Published in:Journal of organic chemistry 2014-02, Vol.79 (3), p.1487-1492
Main Authors: Yang, Hai-Tao, Xing, Meng-Lei, Zhu, Ye-Fei, Sun, Xiao-Qiang, Cheng, Jiang, Miao, Chun-Bao, Li, Fa-Bao
Format: Article
Language:English
Subjects:
Aziridines - chemistry
Boron Compounds - chemistry
Catalysis
Fullerenes - chemistry
Molecular Structure
Oxazoles - chemistry
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Description
Summary:The BF3·Et2O-catalyzed formal [3 + 2] reaction of aziridinofullerenes with various carbonyl compounds for the easy preparation of fullerooxazolidines has been developed. Moreover, the reaction of aziridinofullerene with ethyl formate affords the simplest fullerooxazole without substituent.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo4025573