Highly stable photoresponsive complex framework formation involves unusual selective hydrogenation of a pyridine derivative

A unique hydrothermal selective hydrogenation process is carried out effectively in a simple and friendly way without adding any precious metal catalysts and hydrogen gas from outside. The self-assembly of the hydrogenated product 3-(4-(pyridin-4-yl)piperidin-1-yl) benzoate (PYPDB) with the zinc ion...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-07, Vol.50 (55), p.7326-7328
Main Authors: Zhang, Jie, Geng, Jianming, Zheng, Guiming, Dai, Jingcao, Fu, Zhiyong
Format: Article
Language:English
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Summary:A unique hydrothermal selective hydrogenation process is carried out effectively in a simple and friendly way without adding any precious metal catalysts and hydrogen gas from outside. The self-assembly of the hydrogenated product 3-(4-(pyridin-4-yl)piperidin-1-yl) benzoate (PYPDB) with the zinc ion produces a highly stable photoactive complex Zn(PYPDB)2 displaying interesting long range electron transfer behavior in the conjugated ring system.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc02584a