High spin polarization induced by the interface hybridization in Co/C composite films

• Published in: Carbon (New York) 2012-10, Vol.50 (12), p.4470-4475
• Main Authors: Fan, Z.W., Li, P., Jiang, E.Y., Bai, H.L.
• Format: Article
• Language: English
• Subjects: Carbon; Carbon-carbon composites; Chemistry; Cobalt; Colloidal state and disperse state; Cross-disciplinary physics: materials science; rheology; Damage; Exact sciences and technology; Fullerenes and related materials; diamonds, graphite; General and physical chemistry; Magnetoresistance; Magnetoresistivity; Materials science; Nanoparticles; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Physics; Polarization; Specific materials; Sputtering; Surface physical chemistry
• ISSN: 0008-6223; 1873-3891
• DOI: 10.1016/j.carbon.2012.05.025

Co/C composite films with 10at.% Co were fabricated by facing-target sputtering and postannealed in vacuum at 300–650°C for 1.5h. Co nanoparticles are dispersed in amorphous carbon matrix and Co–C compounds exist at the interface between Co nanoparticles and carbon matrix. Negative magnetoresistance was observed in the Co/C films and its maximum value of −19% was measured at 3.98×106A/m and 5K for the as-deposited film. Besides cotunneling effect, higher interfacial spin polarization, which is probably induced by the hybridization between Co 3d and C 2p electrons and consequently the preferred d-electron conduction and interfacial spin-filtering effect, also contributes to the large negative magnetoresistance. Postannealing treatment damages the interface hybridization, and thus leads to the disappearance of the higher interfacial spin polarization and large negative magnetoresistance.