Effects of various surfactants on the dispersion stability and electrical conductivity of surface modified graphene

• Published in: Journal of alloys and compounds 2013-06, Vol.562, p.134-142
• Main Authors: Uddin, Md. Elias, Kuila, Tapas, Nayak, Ganesh Chandra, Kim, Nam Hoon, Ku, Bon-Cheol, Lee, Joong Hee
• Format: Article
• Language: English
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Dispersions; Electrical conductivity; Electrical resistivity; Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures; Electronic transport in multilayers, nanoscale materials and structures; Exact sciences and technology; Graphene; Physics; Resistivity; Sodium; Stability; Surface modification; Surfactants; Triton; UV–vis spectroscopy; Water dispersibility; X-ray photoelectron spectroscopy
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2013.01.127

[Display omitted] . ► Water dispersible graphene has been prepared using ionic and non-ionic surfactants. ► XPS and FTIR spectra analysis confirm surface modification and reduction of GO. ► The highest water dispersibility is observed in the graphene modified with of SDBS. ► The best properties of modified graphene is achieved with GO/surfactant ratio of two. Ionic and non-ionic surfactant functionalized, water dispersible graphene were prepared to investigate the effects on the dispersion stability and electrical conductivity of graphene. In this study, sodium dodecyl benzene sulfonate (SDBS), sodium dodecyl sulfate and 4-(1,1,3,3-tetramethylbutyl) phenyl-polyethylene glycol (Triton X-100) were used as ionic and non-ionic surfactants. The effects of surfactant concentrations on the dispersibility and electrical conductivity of the surface modified graphene were investigated. The dispersion stability of SDBS functionalized graphene (SDBS-G) was found to be best in water at 1.5mgml−1. X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy analysis indicate that the presence of surfactants does not prevent the reduction of graphene oxide (GO). These measurements also demonstrated that the surfactants were present on the surface of graphene, resulting in the formation of functionalized graphene. The thickness of different functionalized graphene was measured by Atomic force microscopy and varied significantly with different surfactants. The thermal properties of the functionalized graphene were also found to be dependent on the nature of the surfactants. The electrical conductivity of SDBS-G (108Sm−1) was comparatively higher than SDS and Triton X-100 functionalized graphene.