Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes

A silver(I)–N-heterocyclic carbene complex has proven to be a potent catalyst for formal hydroboration of alkynes, providing a variety of borylalkenes in regio- and stereoselective manners. Under the silver catalysis, allenes also undergo regioselective hydroboration to give borylalkenes.

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Bibliographic Details
Published in:Organic letters 2014-07, Vol.16 (13), p.3512-3515
Main Authors: Yoshida, Hiroto, Kageyuki, Ikuo, Takaki, Ken
Format: Article
Language:English
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Summary:A silver(I)–N-heterocyclic carbene complex has proven to be a potent catalyst for formal hydroboration of alkynes, providing a variety of borylalkenes in regio- and stereoselective manners. Under the silver catalysis, allenes also undergo regioselective hydroboration to give borylalkenes.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol501465x