Enhancement of (stereo)selectivity in dynamic kinetic resolution using a core-shell nanozeolite@enzyme as a bi-functional catalyst

A core-shell nanozeolite@enzyme bi-functional catalyst is constructed, which greatly improves selectivity and stereoselectivity of products in dynamic kinetic resolution of aromatic secondary alcohols compared with mixed catalysts, especially those involving small acyl donors.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (67), p.9501-9504
Main Authors: Wang, Wanlu, Li, Xiang, Wang, Zhoujun, Tang, Yi, Zhang, Yahong
Format: Article
Language:English
Subjects:
Benzyl Alcohols - chemistry
Biocatalysis
Fungal Proteins - metabolism
Kinetics
Lipase - metabolism
Nanoparticles - chemistry
Stereoisomerism
Substrate Specificity
Zeolites - chemistry
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Description
Summary:A core-shell nanozeolite@enzyme bi-functional catalyst is constructed, which greatly improves selectivity and stereoselectivity of products in dynamic kinetic resolution of aromatic secondary alcohols compared with mixed catalysts, especially those involving small acyl donors.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc02112f