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Bioactivity potential of calcium alumino-silicate glasses and glass–ceramics containing nitrogen and fluorine
Calcium alumino-silicate glasses of general composition (in eq.%) 28Ca:57Si:15Al:[100 − ( x + y )]O: x N: y F ( x = 0 or 20 and y = 0, 3 or 5) and their glass–ceramic counterparts were immersed in simulated body fluid (SBF) at 37 ± 0.5 °C for 28 days to assess their potential bioactivity. The gl...
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| Published in: | Journal of materials science 2014-07, Vol.49 (13), p.4590-4594 |
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| Main Authors: | , , , |
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| cited_by | cdi_FETCH-LOGICAL-c422t-824e2d65153125c7fe41476829f90c2f32f44a9a1f1a38bc9fdc45ba7b1e54a03 |
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| cites | cdi_FETCH-LOGICAL-c422t-824e2d65153125c7fe41476829f90c2f32f44a9a1f1a38bc9fdc45ba7b1e54a03 |
| container_end_page | 4594 |
| container_issue | 13 |
| container_start_page | 4590 |
| container_title | Journal of materials science |
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| creator | Hanifi, A. R. Crowley, C. M. Pomeroy, M. J. Hampshire, Stuart |
| description | Calcium alumino-silicate glasses of general composition (in eq.%) 28Ca:57Si:15Al:[100 − (
x
+
y
)]O:
x
N:
y
F (
x
= 0 or 20 and
y
= 0, 3 or 5) and their glass–ceramic counterparts were immersed in simulated body fluid (SBF) at 37 ± 0.5 °C for 28 days to assess their potential bioactivity. The glasses showed no Ca release or surface calcium phosphate deposition due to their high network connectivities (>2.55). The glass–ceramics all showed potential bioactivity, as the SBF became enriched in Ca and calcium phosphate deposits formed on their surfaces. This was a result of Ca release from crystalline phases (predominantly wollastonite in the case of CaSiAlOF glass–ceramics and gehlenite in the case of CaSiAlONF glass–ceramics). No aluminium was leached from the glass–ceramics into the SBF, due to its pH always exceeding 7.0. |
| doi_str_mv | 10.1007/s10853-014-8159-6 |
| format | article |
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x
+
y
)]O:
x
N:
y
F (
x
= 0 or 20 and
y
= 0, 3 or 5) and their glass–ceramic counterparts were immersed in simulated body fluid (SBF) at 37 ± 0.5 °C for 28 days to assess their potential bioactivity. The glasses showed no Ca release or surface calcium phosphate deposition due to their high network connectivities (>2.55). The glass–ceramics all showed potential bioactivity, as the SBF became enriched in Ca and calcium phosphate deposits formed on their surfaces. This was a result of Ca release from crystalline phases (predominantly wollastonite in the case of CaSiAlOF glass–ceramics and gehlenite in the case of CaSiAlONF glass–ceramics). No aluminium was leached from the glass–ceramics into the SBF, due to its pH always exceeding 7.0.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-014-8159-6</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Aluminosilicates ; Aluminum ; Aluminum silicates ; Biochemistry ; Biocompatibility ; Biological activity ; Biomedical materials ; Body fluids ; Calcium ; Calcium aluminate ; Calcium aluminum silicates ; Calcium phosphate ; Calcium phosphates ; Ceramic materials ; Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Deposition ; Fluorides ; Fluorine ; Gehlenite ; Glass ; Glass ceramics ; In vitro methods and tests ; Materials Science ; Phosphates ; Polymer Sciences ; Silicates ; Solid Mechanics ; Surgical implants ; Wollastonite</subject><ispartof>Journal of materials science, 2014-07, Vol.49 (13), p.4590-4594</ispartof><rights>Springer Science+Business Media New York 2014</rights><rights>COPYRIGHT 2014 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2014). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-824e2d65153125c7fe41476829f90c2f32f44a9a1f1a38bc9fdc45ba7b1e54a03</citedby><cites>FETCH-LOGICAL-c422t-824e2d65153125c7fe41476829f90c2f32f44a9a1f1a38bc9fdc45ba7b1e54a03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Hanifi, A. R.</creatorcontrib><creatorcontrib>Crowley, C. M.</creatorcontrib><creatorcontrib>Pomeroy, M. J.</creatorcontrib><creatorcontrib>Hampshire, Stuart</creatorcontrib><title>Bioactivity potential of calcium alumino-silicate glasses and glass–ceramics containing nitrogen and fluorine</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Calcium alumino-silicate glasses of general composition (in eq.%) 28Ca:57Si:15Al:[100 − (
x
+
y
)]O:
x
N:
y
F (
x
= 0 or 20 and
y
= 0, 3 or 5) and their glass–ceramic counterparts were immersed in simulated body fluid (SBF) at 37 ± 0.5 °C for 28 days to assess their potential bioactivity. The glasses showed no Ca release or surface calcium phosphate deposition due to their high network connectivities (>2.55). The glass–ceramics all showed potential bioactivity, as the SBF became enriched in Ca and calcium phosphate deposits formed on their surfaces. This was a result of Ca release from crystalline phases (predominantly wollastonite in the case of CaSiAlOF glass–ceramics and gehlenite in the case of CaSiAlONF glass–ceramics). No aluminium was leached from the glass–ceramics into the SBF, due to its pH always exceeding 7.0.</description><subject>Aluminosilicates</subject><subject>Aluminum</subject><subject>Aluminum silicates</subject><subject>Biochemistry</subject><subject>Biocompatibility</subject><subject>Biological activity</subject><subject>Biomedical materials</subject><subject>Body fluids</subject><subject>Calcium</subject><subject>Calcium aluminate</subject><subject>Calcium aluminum silicates</subject><subject>Calcium phosphate</subject><subject>Calcium phosphates</subject><subject>Ceramic materials</subject><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Deposition</subject><subject>Fluorides</subject><subject>Fluorine</subject><subject>Gehlenite</subject><subject>Glass</subject><subject>Glass ceramics</subject><subject>In vitro methods and tests</subject><subject>Materials Science</subject><subject>Phosphates</subject><subject>Polymer Sciences</subject><subject>Silicates</subject><subject>Solid Mechanics</subject><subject>Surgical implants</subject><subject>Wollastonite</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp1kcuKFDEUhoMo2I4-gLsCN7qoMSeV1GU5Dl4GBgQv63A6fVJkSCVtkhJn5zv4hj6JaUuQESSLhPD94c_5GHsK_Bw4H15m4KPqWg6yHUFNbX-P7UANXStH3t1nO86FaIXs4SF7lPMN51wNAnYsvnIRTXFfXbltjrFQKA59E21j0Bu3Lg36dXEhttl5Z7BQM3vMmXKD4bCdf37_YSjh4kxuTAwFXXBhboIrKc4UfoPWrzG5QI_ZA4s-05M_-xn7_Ob1p8t37fX7t1eXF9etkUKUdhSSxKFXoDoQygyWJMihH8VkJ26E7YSVEicEC9iNezPZg5Fqj8MeSEnk3Rl7vr17TPHLSrnoxWVD3mOguGYNSgGfQPRdRZ_9g97ENYXaTguhJiVggL5S5xs1oyftgo0loanrQPXjMZB19f6iG6qOOlxZAy_uBE6ToW9lxjVnffXxw10WNtakmHMiq4_JLZhuNXB98qs3v7r61Se_-lRIbJlc2TBT-lv7_6Ffsgqo0A</recordid><startdate>20140701</startdate><enddate>20140701</enddate><creator>Hanifi, A. R.</creator><creator>Crowley, C. M.</creator><creator>Pomeroy, M. J.</creator><creator>Hampshire, Stuart</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140701</creationdate><title>Bioactivity potential of calcium alumino-silicate glasses and glass–ceramics containing nitrogen and fluorine</title><author>Hanifi, A. R. ; Crowley, C. M. ; Pomeroy, M. J. ; Hampshire, Stuart</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-824e2d65153125c7fe41476829f90c2f32f44a9a1f1a38bc9fdc45ba7b1e54a03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Aluminosilicates</topic><topic>Aluminum</topic><topic>Aluminum silicates</topic><topic>Biochemistry</topic><topic>Biocompatibility</topic><topic>Biological activity</topic><topic>Biomedical materials</topic><topic>Body fluids</topic><topic>Calcium</topic><topic>Calcium aluminate</topic><topic>Calcium aluminum silicates</topic><topic>Calcium phosphate</topic><topic>Calcium phosphates</topic><topic>Ceramic materials</topic><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Deposition</topic><topic>Fluorides</topic><topic>Fluorine</topic><topic>Gehlenite</topic><topic>Glass</topic><topic>Glass ceramics</topic><topic>In vitro methods and tests</topic><topic>Materials Science</topic><topic>Phosphates</topic><topic>Polymer Sciences</topic><topic>Silicates</topic><topic>Solid Mechanics</topic><topic>Surgical implants</topic><topic>Wollastonite</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hanifi, A. R.</creatorcontrib><creatorcontrib>Crowley, C. M.</creatorcontrib><creatorcontrib>Pomeroy, M. J.</creatorcontrib><creatorcontrib>Hampshire, Stuart</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><collection>Aluminium Industry Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hanifi, A. R.</au><au>Crowley, C. M.</au><au>Pomeroy, M. J.</au><au>Hampshire, Stuart</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bioactivity potential of calcium alumino-silicate glasses and glass–ceramics containing nitrogen and fluorine</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2014-07-01</date><risdate>2014</risdate><volume>49</volume><issue>13</issue><spage>4590</spage><epage>4594</epage><pages>4590-4594</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Calcium alumino-silicate glasses of general composition (in eq.%) 28Ca:57Si:15Al:[100 − (
x
+
y
)]O:
x
N:
y
F (
x
= 0 or 20 and
y
= 0, 3 or 5) and their glass–ceramic counterparts were immersed in simulated body fluid (SBF) at 37 ± 0.5 °C for 28 days to assess their potential bioactivity. The glasses showed no Ca release or surface calcium phosphate deposition due to their high network connectivities (>2.55). The glass–ceramics all showed potential bioactivity, as the SBF became enriched in Ca and calcium phosphate deposits formed on their surfaces. This was a result of Ca release from crystalline phases (predominantly wollastonite in the case of CaSiAlOF glass–ceramics and gehlenite in the case of CaSiAlONF glass–ceramics). No aluminium was leached from the glass–ceramics into the SBF, due to its pH always exceeding 7.0.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10853-014-8159-6</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-2461 |
| ispartof | Journal of materials science, 2014-07, Vol.49 (13), p.4590-4594 |
| issn | 0022-2461 1573-4803 |
| language | eng |
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| source | Springer Nature:Jisc Collections:Springer Nature Read and Publish 2023-2025: Springer Reading List |
| subjects | Aluminosilicates Aluminum Aluminum silicates Biochemistry Biocompatibility Biological activity Biomedical materials Body fluids Calcium Calcium aluminate Calcium aluminum silicates Calcium phosphate Calcium phosphates Ceramic materials Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Deposition Fluorides Fluorine Gehlenite Glass Glass ceramics In vitro methods and tests Materials Science Phosphates Polymer Sciences Silicates Solid Mechanics Surgical implants Wollastonite |
| title | Bioactivity potential of calcium alumino-silicate glasses and glass–ceramics containing nitrogen and fluorine |
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