Loading…
Disupersilylperoxo Radical Anion [tBu3SiOOSitBu3]⋅−: An Intermediate of Supersilanide Oxidation
In the oxidative process of the supersilanide anion [SitBu3]−, radical species are generated. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] with O2 revealed a signal, which could be characterized as disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium...
Saved in:
Published in: | Chemistry : a European journal 2014-08, Vol.20 (33), p.10236-10239 |
---|---|
Main Authors: | , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c5184-bf3a4e1cf70a1a5539079433ba75bb18c0eeb5ab841f70a818429d9d1091f0233 |
---|---|
cites | cdi_FETCH-LOGICAL-c5184-bf3a4e1cf70a1a5539079433ba75bb18c0eeb5ab841f70a818429d9d1091f0233 |
container_end_page | 10239 |
container_issue | 33 |
container_start_page | 10236 |
container_title | Chemistry : a European journal |
container_volume | 20 |
creator | Budanow, Alexandra Haeri, Haleh Hashemi Sänger, Inge Schödel, Frauke Bolte, Michael Prisner, Thomas Wagner, Matthias Lerner, Hans-Wolfram |
description | In the oxidative process of the supersilanide anion [SitBu3]−, radical species are generated. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] with O2 revealed a signal, which could be characterized as disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium ions though ion‐pair formation. A mechanism is suggested for the oxidative process of supersilanide, which in a further step can be helpful in a better understanding of the oxidation process of isoelectronic phosphanes.
The oxidative process of the supersilanide anion [SitBu3]− was monitored by EPR spectroscopy. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] and O2 revealed a signal, which could be characterized as the disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium ions through ion‐pair formation (see scheme). |
doi_str_mv | 10.1002/chem.201403854 |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1551331167</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3390118801</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5184-bf3a4e1cf70a1a5539079433ba75bb18c0eeb5ab841f70a818429d9d1091f0233</originalsourceid><addsrcrecordid>eNqFkE2L1EAQhhtR3NnVq0cJePGSsSrVnaS9reN-weqgsyoo0nSSDvZuJhm7E5z5AYLgzZ-4v8QOMw7ixVM19PM-VL2MPUKYIkDyrPxiltMEkAPlgt9hExQJxpSl4i6bgORZnAqSB-zQ-2sAkCnRfXaQCOBJCnLCypfWDyvjvG02TZjduove6sqWuomOW9u10af-xUALO58v7Pj6fPvz--2PX8_Db3TR9sYtTWV1b6KujhY7k25tZaL52la6D4oH7F6tG28e7uYRe3d6cjU7jy_nZxez48u4FJjzuKhJc4NlnYFGLcLakElOVOhMFAXmJRhTCF3kHEckD5lEVrJCkFhDQnTEnm69K9d9HYzv1dL60jRhH9MNXqEQSISYZgF98g963Q2uDduNFJAgIZJATbdU6TrvnanVytmldhuFoMb61Vi_2tcfAo932qEIvezxP30HQG6Bb7Yxm__o1Oz85NXf8nibtb43631WuxsVLsqE-vD6TKVXHyW9eS8Up9_WbaFB</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1550353552</pqid></control><display><type>article</type><title>Disupersilylperoxo Radical Anion [tBu3SiOOSitBu3]⋅−: An Intermediate of Supersilanide Oxidation</title><source>Wiley</source><creator>Budanow, Alexandra ; Haeri, Haleh Hashemi ; Sänger, Inge ; Schödel, Frauke ; Bolte, Michael ; Prisner, Thomas ; Wagner, Matthias ; Lerner, Hans-Wolfram</creator><creatorcontrib>Budanow, Alexandra ; Haeri, Haleh Hashemi ; Sänger, Inge ; Schödel, Frauke ; Bolte, Michael ; Prisner, Thomas ; Wagner, Matthias ; Lerner, Hans-Wolfram</creatorcontrib><description>In the oxidative process of the supersilanide anion [SitBu3]−, radical species are generated. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] with O2 revealed a signal, which could be characterized as disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium ions though ion‐pair formation. A mechanism is suggested for the oxidative process of supersilanide, which in a further step can be helpful in a better understanding of the oxidation process of isoelectronic phosphanes.
The oxidative process of the supersilanide anion [SitBu3]− was monitored by EPR spectroscopy. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] and O2 revealed a signal, which could be characterized as the disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium ions through ion‐pair formation (see scheme).</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201403854</identifier><identifier>PMID: 25042609</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Chemistry ; density functional calculations ; EPR spectroscopy ; Oxidation ; oxygen ; silyl anions ; X-ray diffraction</subject><ispartof>Chemistry : a European journal, 2014-08, Vol.20 (33), p.10236-10239</ispartof><rights>2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5184-bf3a4e1cf70a1a5539079433ba75bb18c0eeb5ab841f70a818429d9d1091f0233</citedby><cites>FETCH-LOGICAL-c5184-bf3a4e1cf70a1a5539079433ba75bb18c0eeb5ab841f70a818429d9d1091f0233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25042609$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Budanow, Alexandra</creatorcontrib><creatorcontrib>Haeri, Haleh Hashemi</creatorcontrib><creatorcontrib>Sänger, Inge</creatorcontrib><creatorcontrib>Schödel, Frauke</creatorcontrib><creatorcontrib>Bolte, Michael</creatorcontrib><creatorcontrib>Prisner, Thomas</creatorcontrib><creatorcontrib>Wagner, Matthias</creatorcontrib><creatorcontrib>Lerner, Hans-Wolfram</creatorcontrib><title>Disupersilylperoxo Radical Anion [tBu3SiOOSitBu3]⋅−: An Intermediate of Supersilanide Oxidation</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>In the oxidative process of the supersilanide anion [SitBu3]−, radical species are generated. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] with O2 revealed a signal, which could be characterized as disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium ions though ion‐pair formation. A mechanism is suggested for the oxidative process of supersilanide, which in a further step can be helpful in a better understanding of the oxidation process of isoelectronic phosphanes.
The oxidative process of the supersilanide anion [SitBu3]− was monitored by EPR spectroscopy. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] and O2 revealed a signal, which could be characterized as the disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium ions through ion‐pair formation (see scheme).</description><subject>Chemistry</subject><subject>density functional calculations</subject><subject>EPR spectroscopy</subject><subject>Oxidation</subject><subject>oxygen</subject><subject>silyl anions</subject><subject>X-ray diffraction</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkE2L1EAQhhtR3NnVq0cJePGSsSrVnaS9reN-weqgsyoo0nSSDvZuJhm7E5z5AYLgzZ-4v8QOMw7ixVM19PM-VL2MPUKYIkDyrPxiltMEkAPlgt9hExQJxpSl4i6bgORZnAqSB-zQ-2sAkCnRfXaQCOBJCnLCypfWDyvjvG02TZjduove6sqWuomOW9u10af-xUALO58v7Pj6fPvz--2PX8_Db3TR9sYtTWV1b6KujhY7k25tZaL52la6D4oH7F6tG28e7uYRe3d6cjU7jy_nZxez48u4FJjzuKhJc4NlnYFGLcLakElOVOhMFAXmJRhTCF3kHEckD5lEVrJCkFhDQnTEnm69K9d9HYzv1dL60jRhH9MNXqEQSISYZgF98g963Q2uDduNFJAgIZJATbdU6TrvnanVytmldhuFoMb61Vi_2tcfAo932qEIvezxP30HQG6Bb7Yxm__o1Oz85NXf8nibtb43631WuxsVLsqE-vD6TKVXHyW9eS8Up9_WbaFB</recordid><startdate>20140811</startdate><enddate>20140811</enddate><creator>Budanow, Alexandra</creator><creator>Haeri, Haleh Hashemi</creator><creator>Sänger, Inge</creator><creator>Schödel, Frauke</creator><creator>Bolte, Michael</creator><creator>Prisner, Thomas</creator><creator>Wagner, Matthias</creator><creator>Lerner, Hans-Wolfram</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20140811</creationdate><title>Disupersilylperoxo Radical Anion [tBu3SiOOSitBu3]⋅−: An Intermediate of Supersilanide Oxidation</title><author>Budanow, Alexandra ; Haeri, Haleh Hashemi ; Sänger, Inge ; Schödel, Frauke ; Bolte, Michael ; Prisner, Thomas ; Wagner, Matthias ; Lerner, Hans-Wolfram</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5184-bf3a4e1cf70a1a5539079433ba75bb18c0eeb5ab841f70a818429d9d1091f0233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Chemistry</topic><topic>density functional calculations</topic><topic>EPR spectroscopy</topic><topic>Oxidation</topic><topic>oxygen</topic><topic>silyl anions</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Budanow, Alexandra</creatorcontrib><creatorcontrib>Haeri, Haleh Hashemi</creatorcontrib><creatorcontrib>Sänger, Inge</creatorcontrib><creatorcontrib>Schödel, Frauke</creatorcontrib><creatorcontrib>Bolte, Michael</creatorcontrib><creatorcontrib>Prisner, Thomas</creatorcontrib><creatorcontrib>Wagner, Matthias</creatorcontrib><creatorcontrib>Lerner, Hans-Wolfram</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Budanow, Alexandra</au><au>Haeri, Haleh Hashemi</au><au>Sänger, Inge</au><au>Schödel, Frauke</au><au>Bolte, Michael</au><au>Prisner, Thomas</au><au>Wagner, Matthias</au><au>Lerner, Hans-Wolfram</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Disupersilylperoxo Radical Anion [tBu3SiOOSitBu3]⋅−: An Intermediate of Supersilanide Oxidation</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2014-08-11</date><risdate>2014</risdate><volume>20</volume><issue>33</issue><spage>10236</spage><epage>10239</epage><pages>10236-10239</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>In the oxidative process of the supersilanide anion [SitBu3]−, radical species are generated. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] with O2 revealed a signal, which could be characterized as disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium ions though ion‐pair formation. A mechanism is suggested for the oxidative process of supersilanide, which in a further step can be helpful in a better understanding of the oxidation process of isoelectronic phosphanes.
The oxidative process of the supersilanide anion [SitBu3]− was monitored by EPR spectroscopy. The continuous wave (cw)‐EPR spectrum of the reaction solution of Na[SitBu3] and O2 revealed a signal, which could be characterized as the disupersilylperoxo radical anion [tBu3SiOOSitBu3]⋅− affected by sodium ions through ion‐pair formation (see scheme).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>25042609</pmid><doi>10.1002/chem.201403854</doi><tpages>4</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0947-6539 |
ispartof | Chemistry : a European journal, 2014-08, Vol.20 (33), p.10236-10239 |
issn | 0947-6539 1521-3765 |
language | eng |
recordid | cdi_proquest_miscellaneous_1551331167 |
source | Wiley |
subjects | Chemistry density functional calculations EPR spectroscopy Oxidation oxygen silyl anions X-ray diffraction |
title | Disupersilylperoxo Radical Anion [tBu3SiOOSitBu3]⋅−: An Intermediate of Supersilanide Oxidation |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T12%3A05%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Disupersilylperoxo%20Radical%20Anion%20%5BtBu3SiOOSitBu3%5D%E2%8B%85%E2%88%92:%20An%20Intermediate%20of%20Supersilanide%20Oxidation&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Budanow,%20Alexandra&rft.date=2014-08-11&rft.volume=20&rft.issue=33&rft.spage=10236&rft.epage=10239&rft.pages=10236-10239&rft.issn=0947-6539&rft.eissn=1521-3765&rft.coden=CEUJED&rft_id=info:doi/10.1002/chem.201403854&rft_dat=%3Cproquest_cross%3E3390118801%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c5184-bf3a4e1cf70a1a5539079433ba75bb18c0eeb5ab841f70a818429d9d1091f0233%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1550353552&rft_id=info:pmid/25042609&rfr_iscdi=true |