Ab Initio Chemical Synthesis of Designer Metal Phosphate Frameworks at Ambient Conditions

Stepwise hierarchical and rational synthesis of porous zinc phosphate frameworks by predictable and directed assembly of easily isolable tetrameric zinc phosphate [Zn(dipp)(solv)]4 (dippH2 = diisopropylphenyldihydrogen phosphate; solv = CH3OH or dimethyl sulfoxide) with D4R (double-4-ring) topology...

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Published in:Inorganic chemistry 2014-09, Vol.53 (17), p.8959-8969
Main Authors: Kalita, Alok Ch, Gogoi, Nayanmoni, Jangir, Ritambhara, Kuppuswamy, Subramaniam, Walawalkar, Mrinalini G, Murugavel, Ramaswamy
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cited_by cdi_FETCH-LOGICAL-a381t-47ed6106ace177f4d010a5265643aa7883d2888ec2178900efb538147386b8683
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container_end_page 8969
container_issue 17
container_start_page 8959
container_title Inorganic chemistry
container_volume 53
creator Kalita, Alok Ch
Gogoi, Nayanmoni
Jangir, Ritambhara
Kuppuswamy, Subramaniam
Walawalkar, Mrinalini G
Murugavel, Ramaswamy
description Stepwise hierarchical and rational synthesis of porous zinc phosphate frameworks by predictable and directed assembly of easily isolable tetrameric zinc phosphate [Zn(dipp)(solv)]4 (dippH2 = diisopropylphenyldihydrogen phosphate; solv = CH3OH or dimethyl sulfoxide) with D4R (double-4-ring) topology has been achieved. The preformed and highly robust D4R secondary building unit can be coordinatively interconnected through a varied choice of bipyridine-based ditopic spacers L1–L7 to isolate eight functional zinc phosphate frameworks, [Zn4(dipp)4(L1)1.5(DMSO)]·4H2O (2), [Zn4(dipp)4(L2)1.5(CH3OH)] (3), [Zn4(dipp)4(L1)2] (4), [Zn4(dipp)4(L3)2] (5), [Zn4(dipp)4(L4)2] (6), [Zn4(dipp)4(L5)2] (7), [Zn4(dipp)4(L6)2] (8), and [Zn4(dipp)4(L7)2] (9), in good yield. The preparative procedures are simple and do not require high pressure or temperature. Surface area measurements of these framework solids show that the guest accessibility of the frameworks can be tuned by suitable modification of bipyridine spacers.
doi_str_mv 10.1021/ic500810d
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title Ab Initio Chemical Synthesis of Designer Metal Phosphate Frameworks at Ambient Conditions
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