Guest-Cage Atomic Interactions in a Clathrate-Based Phase-Change Material

New clathrate‐based phase‐change materials with cage‐like structures incorporating Cs and Ba guest atoms, are reported as a means of altering crystallization and amorphization behavior by controlling ‘guest‐cage’ interactions via intra‐complex guest vibrational effects. Both a high resistance to spo...

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Published in:Advanced materials (Weinheim) 2014-03, Vol.26 (11), p.1725-1730
Main Authors: Loke, Desmond, Skelton, Jonathan M., Law, Leong-Tat, Wang, Wei-Jie, Li, Ming-Hua, Song, Wen-Dong, Lee, Tae-Hoon, Elliott, Stephen R.
Format: Article
Language:English
Subjects:
Amorphization
Atomic interactions
Atomic structure
clathrate compounds
Crystallization
crystallization kinetics
guest-cage interactions
High resistance
Melting
nano-engineering
phase-change materials
Semiconductor devices
Spontaneous
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container_end_page 1730
container_issue 11
container_start_page 1725
container_title Advanced materials (Weinheim)
container_volume 26
creator Loke, Desmond
Skelton, Jonathan M.
Law, Leong-Tat
Wang, Wei-Jie
Li, Ming-Hua
Song, Wen-Dong
Lee, Tae-Hoon
Elliott, Stephen R.
description New clathrate‐based phase‐change materials with cage‐like structures incorporating Cs and Ba guest atoms, are reported as a means of altering crystallization and amorphization behavior by controlling ‘guest‐cage’ interactions via intra‐complex guest vibrational effects. Both a high resistance to spontaneous crystallization, and long retention of the amorphous phase are achieved, as well as a low melting energy. This approach provides a route for achieving cage‐controlled semiconductor devices.
doi_str_mv 10.1002/adma.201304199
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source Wiley-Blackwell Read & Publish Collection
subjects Amorphization
Atomic interactions
Atomic structure
clathrate compounds
Crystallization
crystallization kinetics
guest-cage interactions
High resistance
Melting
nano-engineering
phase-change materials
Semiconductor devices
Spontaneous
title Guest-Cage Atomic Interactions in a Clathrate-Based Phase-Change Material
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