Fuel Cells: Nano-Intermetallic AuCu sub(3) Catalyst for Oxygen Reduction Reaction: Performance and Mechanism (Small 13/2014)

Au-segregated intermetallic AuCu sub(3)/C nanoparticles with uniform dispersion and narrow size distribution around 3 nm are reported by D. Xia, J. Li, and colleagues on page 2662. These nanoparticles have excellent catalytic performance for ORR in alkaline solution, excellent durability, as well as...

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Bibliographic Details
Published in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2014-07, Vol.10 (13), p.2661-2661
Main Authors: Zhang, Nanlin, Chen, Xin, Lu, Yuanjun, An, Li, Li, Xiang, Xia, Dingguo, Zhang, Ze, Li, Jixue
Format: Article
Language:English
Subjects:
Catalysts
Copper
Dispersions
Gold
Methyl alcohol
Nanoparticles
Surface chemistry
Tolerances
Online Access:Get full text
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Summary:Au-segregated intermetallic AuCu sub(3)/C nanoparticles with uniform dispersion and narrow size distribution around 3 nm are reported by D. Xia, J. Li, and colleagues on page 2662. These nanoparticles have excellent catalytic performance for ORR in alkaline solution, excellent durability, as well as methanol tolerance activities. The enhanced activities mainly result from the synergetic effects between electroactive Au and Cu atoms on the particle surface: Cu activates O sub(2) adsorption, and Au promotes OH-desorption.
ISSN:1613-6810
1613-6829
DOI:10.1002/smll.201470077