Influence of Pore Fluid Chemistry on the Mechanical Properties of Clay-Based Materials

• Published in: Geotechnical and geological engineering 2014-08, Vol.32 (4), p.1029-1042
• Main Authors: Siddiqua, Sumi, Siemens, Greg, Blatz, James, Man, Alex, Lim, Bee Fong
• Format: Article
• Language: English
• Subjects: Backfill; Bentonite; Chemistry; Civil Engineering; Clay; Clay (material); Compressibility; Computer simulation; Containers; Earth and Environmental Science; Earth Sciences; Fluid flow; Fluids; Freshwater; Geology; Geosphere; Geotechnical Engineering & Applied Earth Sciences; Glacial lakes; Groundwater; Hydrogeology; Light; Light effects; Material properties; Mathematical models; Mechanical analysis; Mechanical properties; Organic chemistry; Original Paper; Radioactive wastes; Repositories; Saline groundwater; Sand; Silica; Silicon dioxide; Terrestrial Pollution; Waste Management/Waste Technology
• ISSN: 0960-3182; 1573-1529
• DOI: 10.1007/s10706-014-9778-z

The producers of nuclear waste, within all countries exploring options, including Canada, have determined the long-term solution to be a deep geological repository. In the Canadian concept, within the deep geologic repository a number of clay-based barriers will separate the containers from the surrounding geosphere. Following placement the surrounding groundwater will infiltrate into the repository. In order to analyze the performance of the repository under very complex conditions, accurate material properties are required. The chemistry of the host rock is an important aspect as the behaviour of clay-based barrier materials could be affected by the saturating saline groundwater. This paper investigates the saturated mechanical behaviour of light backfill (composed of 50 % silica sand and 50 % Na-bentonite clay) and dense backfill (composed of 70 % crushed granite, 25 % glacial lake clay and 5 % Na-bentonite clay) and the quantifying the effect of pore fluid chemistry on the strength and compressibility behaviour of the materials. The results indicate that light backfill behaviour is strongly influenced by its pore fluid chemistry while dense backfill shows limited effects. The material parameters of light backfill and dense backfill are interpreted for input into numerical simulations. These results and interpretation enrich the understanding of the mechanical response of light and dense backfill, two components of the sealing system of the Canadian deep geologic repository.