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Use of Multilayered Ni-Sn and Ni-Sn-C Thin Film Anodes for Lithium-Ion Batteries
This study explores the electrochemical performance of Ni-Sn and Ni-Sn-C thin film anodes in rechargeable lithium-ion batteries. A new strategy of forming a Ni-Sn-C multilayered thin film is proposed here, where nickel-coated carbon powder is used as a source material to incorporate carbon atoms int...
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Published in: | Electrochimica acta 2014-07, Vol.135, p.585-593 |
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container_title | Electrochimica acta |
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creator | Polat, B.D. Abouimrane, A. Sezgin, N. Keles, O. Amine, K. |
description | This study explores the electrochemical performance of Ni-Sn and Ni-Sn-C thin film anodes in rechargeable lithium-ion batteries. A new strategy of forming a Ni-Sn-C multilayered thin film is proposed here, where nickel-coated carbon powder is used as a source material to incorporate carbon atoms into the thin film in a controlled manner. Galvanostatic half-cell measurements demonstrated that the Ni-Sn thin film shows a gradually decreasing capacity with cycling, whereas the Ni-Sn-C thin film exhibits a longer cycle life with good capacity retention. The improved cycle performance of the Ni-Sn-C electrode is attributed to its high tolerance against electrode swelling, which is closely associated with the stress-buffering action of nickel and the homogeneous distribution on nanoparticles induced by carbon. |
doi_str_mv | 10.1016/j.electacta.2014.05.024 |
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subjects | Anodes Carbon Electrodes Electron beam evaporation Lithium-ion batteries Ni-Sn thin film anode Nickel Swelling Thin films Tolerances |
title | Use of Multilayered Ni-Sn and Ni-Sn-C Thin Film Anodes for Lithium-Ion Batteries |
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